journal article·2008-01-07

Polymerizable Photochromic Macrocyclic Metallomesogens: Design of Supramolecular Polymers with Responsive Nanopores

C. S. Pecinovsky, E. S. Hatakeyama, D. L. Gin

Advanced Materials· Volume 20· Issue 1
Publisher page

Abstract

A liquid-crystalline (LC) monomer containing a bis(azobenzene)-based metallomacrocycle was synthesized and found to form a columnar hexagonal (ColH) LC phase. Adding solvent to swell the cross-linked ColH phase allows the azobenzene macrocycles to undergo photo-isomerization from the “closed” to “open” form with retention of LC order to afford a supramolecular polymer with photo-responsive nanopores.
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Research context

OpenAlex topics: Supramolecular Self-Assembly in Materials · Liquid Crystal Research Advancements · Photochromic and Fluorescence Chemistry

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

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