journal article·2009-03-20

Blue‐Gap Poly(p‐phenylene vinylene)s with Fluorinated Double Bonds: Interplay Between Supramolecular Organization and Optical Properties in Thin Films

Maria Losurdo, Maria M. Giangregorio, Pio Capezzuto, Antonio Cardone, Carmela Martinelli, Gianluca M. Farinola, Francesco Babudri, Francesco Naso, Michael Büchel, Giovanni Bruno

Advanced Materials· Volume 21· Issue 10-11
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Abstract

Blue-light-emitting poly(p-phenylene vinylene)s with fluorinated vinylene units are presented. It is demonstrated that self-aggregation governs the strength and polarization of the absorption spectra of thin films of these polymers. This indicates that self-assembly of the polymer chains in the films provides a means of tuning the electronic and optical properties of the π-conjugated systems.
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Research context

OpenAlex topics: Luminescence and Fluorescent Materials · Organic Electronics and Photovoltaics · Conducting polymers and applications

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