journal article·1997-01Open access

Design of strongly NLO‐active molecularly‐based ferromagnets

Sophie Bénard, Pei Yu, Thibaud Coradin, Eric Rivière, Keitaro Nakatani, René Clément

Advanced Materials· Volume 9· Issue 12

Abstract

Molecule‐based ferromagnets that exhibit strong second‐harmonic generation (SHG) are presented here for the first time. The strategy for producing such materials—replace the “innocent” bulky cations (C) in the C[M′M(ox)3] family of bimetallic magnets (M′ is e.g. Mn and M = CrIII or FeIII; the Figure shows the structure) by hyperpolarizable cationic chromophores—is described and X‐ray, magnetic, and SHG results are reported.magnified image
Source: crossref · Quality: baseline

Research context

OpenAlex topics: Magnetism in coordination complexes · Organic and Molecular Conductors Research · Electron Spin Resonance Studies

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (14)

Show source-provided references
1. 10.1007/978-94-011-3254-110.1007/978-94-011-3254-1 ↗
2. 10.1002/anie.19940385110.1002/anie.199403851 ↗
3. 10.1038/378701a010.1038/378701a0 ↗
4. 10.1126/science.261.5120.44710.1126/science.261.5120.447 ↗
5. Kahn O. · 1993
6. 10.1021/ja952301s10.1021/ja952301s ↗
7. 10.1126/science.272.5262.70410.1126/science.272.5262.704 ↗
8. 10.1126/science.263.5147.65810.1126/science.263.5147.658 ↗
9. 10.1021/ja00044a00410.1021/ja00044a004 ↗
10. (a)H.Tamaki M.Mitsumi K.Nakamura N.Matsumoto S.Kida H.Okawa S.Iijima Chem. Lett.1992 1975.
11. (b)C.Mathoniere S. G.Carling D.Yusheng P.Day J. Chem. Soc. Chem. Commun.1994 1551.10.1039/C39940001551 ↗
12. Atovmyan L. O. · JETP Lett. · 1993 · 10 · 766
13. 10.1016/0020-1693(93)03711-I10.1016/0020-1693(93)03711-I ↗
14. Indexation of the X‐ray diffraction pattern of [MnCr] (Table 2). We note that I = 3n and therefore the pattern could actually be indexed with a c axis three times smaller. The purpose of this indexation is simply to show that the unit cell determined for the reference compound can account for the reflections of [MnCr].