journal article·2005-07-18

From Coordination Polymer Macrocrystals to Nanometric Individual Chains

D. Olea, S. S. Alexandre, P. Amo‐Ochoa, A. Guijarro, F. de Jesús, J. M. Soler, P. J. de Pablo, F. Zamora, J. Gómez‐Herrero

Advanced Materials· Volume 17· Issue 14
Publisher page

Abstract

Isolated single chains of the coordination polymer [Cd(6-MCP)2 · 2H2O]n (6-MCP = 6-mercaptopurinate) (see Figure and inside cover) have been prepared by ultrasonic dispersion, ultracentrifugation, and deposition on a treated mica surface, and their mechanical and electrical properties studied. The observed insulating behaviour of the chains has been confirmed using density functional theory calculations.
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Research context

OpenAlex topics: Metal-Organic Frameworks: Synthesis and Applications · Corrosion Behavior and Inhibition · Crystallography and molecular interactions

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