journal article·1999-12Open access

Formation of Hollow Helicoids in Mesoporous Silica: Supramolecular Origami

S. M. Yang, I. Sokolov, N. Coombs, C. T. Kresge, G. A. Ozin

Advanced Materials· Volume 11· Issue 17

Abstract

Siliceous hollow helicoids (Archimedian screw shapes) with spiraling mesoscale channels are the result of a new way of controlling the growth and form of hexagonal mesoporous silica. These novel helicoids (see Figure) are produced when a patch of the hexagonal silicate liquid-crystal film contracts on hydrolytic polycondensation, triggering “roll-up”. A supramolecular Origami theoretical model is invoked to rationalize hollow helicoid formation.
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Research context

OpenAlex topics: Mesoporous Materials and Catalysis · Diatoms and Algae Research · Aerogels and thermal insulation

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