meso‐(Tetraphenylporphinato)manganese(III)‐tetracyanoethenide, [MnIIITPP]::⊕[TCNE].⊖. A New Structure‐Type Linear‐Chain Magnet with a Tc of 18K
Source abstract
Abstract
Cooperative magnetic interactions in molecular materials at room temperature are the goal of much interdisciplinary research. The title compound is shown to have a Tc of 18 K and to be of a new structural type which makes it a suitable model for the previously reported, disordered, infusible V(TCNE), which is a room‐temperature magnet. The synthesis and structure of the new material are discussed.
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Research context
OpenAlex topics: Magnetism in coordination complexes · Porphyrin and Phthalocyanine Chemistry · Organic and Molecular Conductors Research
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (37)
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27. (a) As the [Fe(C5Me5)2].⊕(ref. 3a) or [Bu4N]⊕salts.
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31. (a) ForgMn=gTCNE= 2 SMN= 2 andSTCNE= 1/2: μeff= μB{[g2S(S+ 1)]Mn+ [g2S(S+ 1)]TCNE}1/2= 5.20 μB.
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37. Other magnetic ordering phenomena at both lower and higher temperatures are also being studied.