Recent advances in cathode catalyst architecture for lithium–oxygen batteries
Source abstract
Abstract
Lithium–oxygen (Li–O2) batteries have great potential for applications in electric devices and vehicles due to their high theoretical energy density of 3500 Wh kg−1. Unfortunately, their practical use is seriously limited by the sluggish decomposition of insulating Li2O2, leading to high OER overpotentials and the decomposition of cathodes and electrolytes. Cathode electrocatalysts with high oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) activities are critical to alleviate high charge overpotentials and promote cycling stability in Li–O2 batteries. However, constructing catalysts for high OER performance and energy efficiency is always challenging. In this mini-review, we first outline the employment of advanced electrocatalysts such as carbon materials, noble and non-noble metals, and metal–organic frameworks to improve battery performance. We then detail the ORR and OER mechanisms of photo-assisted electrocatalysts and single-atom catalysts for superior Li–O2 battery performance. Finally, we offer perspectives on future development directions for cathode electrocatalysts that will boost the OER kinetics.
Source: openalex_inverted_index · Quality: baseline
Research context
OpenAlex topics: Advanced Battery Materials and Technologies · Advancements in Battery Materials · Electrocatalysts for Energy Conversion
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (100+)
Show source-provided references
1. Irreplaceable carbon boosts Li-O2 batteries: from mechanism research to practical application10.1016/j.nanoen.2021.106464 ↗
2. Tuning the structure and morphology of Li2O2 by controlling the crystallinity of catalysts for Li-O2 batteries10.1016/j.cej.2020.128145 ↗
3. Ultrathin Co3O4 nanosheets with edge-enriched {111} planes as efficient catalysts for lithium–oxygen batteries10.1021/acscatal.8b05182 ↗
4. Semiconducting metal–organic polymer nanosheets for a photoinvolved Li–O2 battery under visible light10.1021/jacs.0c11400 ↗
5. Tailoring the adsorption behavior of superoxide intermediates on nickel carbide enables high-rate Li–O2 batteries10.1016/j.esci.2022.06.002 ↗
6. Single-atom catalyst cathodes for lithium–oxygen batteries: a review10.1088/2399-1984/ac3ec1 ↗
7. Innovative electrochemical strategies for hydrogen production: from electricity input to electricity output
8. Induced construction of large-area amorphous Li2O2 film via elemental co-doping and spatial confinement to achieve high-performance Li-O2 batteries
9. Photo-energy conversion and storage in an aprotic Li-O2 battery10.1002/ange.201911228 ↗
10. A polymer electrolyte-based rechargeable lithium/oxygen battery10.1149/1.1836378 ↗
11. Rechargeable Li2O2 electrode for lithium batteries10.1021/ja056811q ↗
12. Study on lithium/air secondary batteries-Stability of NASICON-type lithium ion conducting glass–ceramics with water10.1016/j.jpowsour.2008.08.009 ↗
13. Influence of nonaqueous solvents on the electrochemistry of oxygen in the rechargeable lithium−air battery10.1021/jp102019y ↗
14. Computational study of the mechanisms of superoxide-induced decomposition of organic carbonate-based electrolytes10.1021/jz1016526 ↗
15. A reversible and higher-rate Li-O2 battery10.1126/science.1223985 ↗
16. Solvating additives drive solution-mediated electrochemistry and enhance toroid growth in non-aqueous Li–O2 batteries10.1038/nchem.2132 ↗
17. Cycling Li-O2 batteries via LiOH formation and decomposition10.1126/science.aac7730 ↗
18. A lithium–oxygen battery based on lithium superoxide10.1038/nature16484 ↗
19. Singlet oxygen formation during the charging process of an aprotic lithium–oxygen battery10.1002/anie.201602142 ↗
20. A high-energy-density lithium-oxygen battery based on a reversible four-electron conversion to lithium oxide10.1126/science.aas9343 ↗
21. Probing the reaction kinetics of the charge reactions of nonaqueous Li–O2 batteries10.1021/jz3018368 ↗
22. A solvent-controlled oxidation mechanism of Li2O2 in lithium-oxygen batteries10.1016/j.joule.2018.07.021 ↗
23. Recent advances in understanding of the mechanism and control of Li2O2 formation in aprotic Li–O2 batteries10.1039/C7CS00255F ↗
24. Functional and stability orientation synthesis of materials and structures in aprotic Li-O2 batteries10.1039/C8CS00009C ↗
25. MoSe2@ CNT core–shell nanostructures as grain promoters featuring a direct Li2O2 formation/decomposition catalytic capability in lithium-oxygen batteries
26. High-capacity and stable Li-O2 batteries enabled by a trifunctional soluble redox mediator10.1002/ange.202009064 ↗
27. Surface mechanism of catalytic electrodes in lithium-oxygen batteries: How nanostructures mediate the interfacial reactions10.1021/jacs.0c07167 ↗
28. Designing a self-healing protective film on a lithium metal anode for long-cycle-life lithium-oxygen batteries
29. A high-performance Li–O2 battery with a strongly solvating hexamethylphosphoramide electrolyte and a LiPON-protected lithium anode10.1002/adma.201701568 ↗
30. Direct in situ spectroscopic evidence for solution-mediated oxygen reduction reaction intermediates in aprotic lithium–oxygen batteries10.1021/acs.nanolett.1c04445 ↗
31. A universal method to fabricating porous carbon for Li-O2 battery10.1016/j.nanoen.2021.105782 ↗
32. Fundamental understanding and material challenges in rechargeable nonaqueous Li–O2 batteries: recent progress and perspective10.1002/aenm.201800348 ↗
33. High-efficient CoPt/activated functional carbon catalyst for Li-O2 batteries10.1016/j.nanoen.2021.105877 ↗
34. Synergistic catalysis of the lattice oxygen and transition metal facilitating ORR and OER in perovskite catalysts for Li–O2 batteries10.1021/acscatal.0c02608 ↗
35. Toward high-performance lithium-oxygen batteries with cobalt-based transition metal oxide catalysts: advanced strategies and mechanical insights10.1002/inf2.12260 ↗
36. Holey 2D nanosheets of low-valent manganese oxides with an excellent oxygen catalytic activity and a high functionality as a catalyst for Li–O2 batteries
37. One-step route synthesized Co2P/Ru/N-doped carbon nanotube hybrids as bifunctional electrocatalysts for high-performance Li–O2 batteries
38. Inward growth of superthin TiC skin on carbon nanotube framework as stable cathode support for Li–O2 batteries
39. Evolution of discharge products on carbon nanotube cathodes in Li–O2 batteries unraveled by molecular dynamics and density functional theory10.1021/acscatal.2c00409 ↗
40. Iridium coated Co nanoparticles embedded into highly porous N-doped carbon nanocubes grafted with carbon nanotubes as a catalytic cathode for high-performance Li–O2 batteries10.1039/D1TA04830A ↗
41. Mesoporous carbon nanocube architecture for high-performance lithium–oxygen batteries10.1002/adfm.201500863 ↗
42. Oxygen-enriched carbon nanotubes as a bifunctional catalyst promote the oxygen reduction/evolution reactions in Li-O2 batteries10.1016/j.carbon.2018.10.025 ↗
43. Brush-like cobalt nitride anchored carbon nanofiber membrane: current collector-catalyst integrated cathode for long cycle Li–O2 batteries10.1021/acsnano.7b03794 ↗
44. In-situ deposition of Pd/Pd4S heterostructure on hollow carbon spheres as efficient electrocatalysts for rechargeable Li-O2 batteries10.1016/j.cclet.2020.11.003 ↗
45. Iron carbide decorated carbon nanosphere-sheet hybrid based rechargeable high-capacity non-aqueous Li–O2 batteries10.1016/j.carbon.2022.04.080 ↗
46. A critical review on functionalization of air-cathodes for nonaqueous Li–O2 batteries10.1002/adfm.201808303 ↗
47. Free-standing air cathodes based on 3D hierarchically porous carbon membranes: kinetic overpotential of continuous macropores in Li-O2 batteries10.1002/ange.201801399 ↗
48. Highly reversible Li-O2 battery induced by modulating local electronic structure via synergistic interfacial interaction between ruthenium nanoparticles and hierarchically porous carbon10.1016/j.nanoen.2018.12.047 ↗
49. Recent advances in electrocatalysts for non-aqueous Li–O2 batteries10.1016/j.cclet.2016.10.023 ↗
50. Recent progress in electrocatalyst for Li-O2 batteries10.1002/aenm.201700875 ↗
51. Recent progress on stability enhancement for cathode in rechargeable non-aqueous lithium-oxygen battery10.1002/aenm.201500633 ↗
52. Recent progress in hierarchically structured O2-cathodes for Li-O2 batteries10.1016/j.cej.2018.06.014 ↗
53. Computational insights into oxygen reduction reaction and initial Li2O2 nucleation on pristine and N-doped graphene in Li–O2 batteries10.1021/acscatal.5b00332 ↗
54. Blood-capillary-inspired, free-standing, flexible, and low-cost super-hydrophobic N-CNTs@SS cathodes for high-capacity, high-rate, and stable Li-air batteries
55. The doping effect on the catalytic activity of graphene for oxygen evolution reaction in a lithium–air battery: a first-principles study10.1039/C5CP00869G ↗
56. Facile synthesis of boron-doped rGO as cathode material for high energy Li–O2 batteries10.1021/acsami.6b05403 ↗
57. Challenges and strategy on parasitic reaction for high-performance nonaqueous lithium-oxygen batteries10.1002/aenm.202001789 ↗
58. Ultraviolet-assisted construction of low-Pt-loaded MXene catalysts for high-performance Li−O2 batteries
59. Recent advances in charge mechanism of noble metal-based cathodes for Li-O2 batteries
60. Oxygen vacancy-rich RuO2–Co3O4 nanohybrids as improved electrocatalysts for Li–O2 batteries10.1021/acsami.1c08720 ↗
61. Porous RuO2 nanosheet/CNT electrodes for DMSO-based Li-O2 and Li ion O2 batteries
62. Decoupling atomic-layer-deposition ultrafine RuO2 for high-efficiency and ultralong-life Li-O2 batteries10.1016/j.nanoen.2017.02.030 ↗
63. A synergistic catalytic mechanism for oxygen evolution reaction in aprotic Li–O2 battery10.1021/acscatal.8b02236 ↗
64. Enhancing the cyclability of Li–O2 batteries using PdM alloy nanoparticles anchored on nitrogen-doped reduced graphene as the cathode catalyst10.1016/j.jpowsour.2016.10.089 ↗
65. Long-life lithium-O2 battery achieved by integrating quasi-solid electrolyte and highly active Pt3Co nanowires catalyst
66. Unraveling the catalytic activities of ruthenium nanocrystals in high performance aprotic Li–O2 batteries10.1016/j.nanoen.2016.08.057 ↗
67. High-energy-density metal-oxygen batteries: lithium-oxygen batteries vs sodium-oxygen batteries10.1002/adma.201606572 ↗
68. Anisotropic surface modulation of Pt catalysts for highly reversible Li-O2 batteries: high index facet as a critical descriptor10.1021/acscatal.8b02172 ↗
69. Engineering eg orbital occupancy of Pt with Au alloying enables reversible Li−O2 batteries
70. Critical challenges in rechargeable aprotic Li-O2 batteries10.1002/aenm.201502303 ↗
71. Reversibility of noble metal-catalyzed aprotic Li-O2 batteries10.1021/acs.nanolett.5b03510 ↗
72. Critically examining the role of nanocatalysts in Li-O2 batteries: viability toward suppression of recharge overpotential, rechargeability, and cyclability10.1021/acsenergylett.8b00054 ↗
73. High rate and long cycle life in Li-O2 batteries with highly efficient catalytic cathode configured with Co3O4 nanoflower10.1016/j.nanoen.2019.103896 ↗
74. Enhancing the catalytic activity of Co3O4 for Li–O2 batteries through the synergy of surface/interface/doping engineering10.1021/acscatal.7b03566 ↗
75. Co3O4 nanocage derived from metal-organic frameworks: an excellent cathode catalyst for rechargeable Li-O2 battery10.1007/s12274-019-2388-6 ↗
76. Improved electrocatalytic activity of δ-MnO2@ MWCNTs by inducing the oriented growth of oxygen reduction products in Li-O2 batteries10.1016/j.nanoen.2019.01.089 ↗
77. α-MnO2 nanowire-anchored highly oxidized cluster as a catalyst for Li-O2 batteries: superior electrocatalytic activity and high functionality10.1002/anie.201809205 ↗
78. High-rate and high-areal-capacity air cathodes with enhanced cycle life based on RuO2/MnO2 bifunctional electrocatalysts supported on CNT for pragmatic Li–O2 batteries10.1021/acscatal.8b00248 ↗
79. Urchin-like NiO–NiCo2O4 heterostructure microsphere catalysts for enhanced rechargeable non-aqueous Li–O2 batteries10.1039/C8NR08457B ↗
80. MOF-Templated sword-like Co3O4@ NiCo2O4 sheet arrays on carbon cloth as highly efficient Li–O2 battery cathode10.1016/j.jpowsour.2020.227725 ↗
81. Bifunctional hybrid catalysts with perovskite LaCo0. 8Fe0. 2O3 nanowires and reduced graphene oxide sheets for an efficient Li–O2 battery cathode10.1021/acsami.7b14599 ↗
82. Porous perovskite La0. 6Sr0. 4Co0. 8Mn0. 2O3 nanofibers loaded with RuO2 nanosheets as an efficient and durable bifunctional catalyst for rechargeable Li–O2 batteries10.1021/acscatal.7b02153 ↗
83. Cesium lead bromide perovskite-based lithium–oxygen batteries10.1021/acs.nanolett.1c01631 ↗
84. Kinetic insight into perovskite La0. 8Sr0. 2VO3 nanofibers as an efficient electrocatalytic cathode for high-rate Li-O2 batteries10.1002/inf2.12243 ↗
85. Perovskite LaCoxMn1–xO3−σ with tunable defect and surface structures as cathode catalysts for Li–O2 batteries10.1021/acsami.9b21904 ↗
86. Cation-exchange-induced metal and alloy dual-exsolution in perovskite ferrite oxides boosting the performance of Li-O2 battery10.1002/ange.202110116 ↗
87. High-performance bi-functional electrocatalysts of 3D crumpled graphene–cobalt oxide nanohybrids for oxygen reduction and evolution reactions10.1039/C3EE42696C ↗
88. An O2 cathode for rechargeable lithium batteries: the effect of a catalyst10.1016/j.jpowsour.2007.06.180 ↗
89. Surface acidity as descriptor of catalytic activity for oxygen evolution reaction in Li-O2 battery10.1021/jacs.5b07792 ↗
90. Heterostructured CoO-Co3O4 nanoparticles anchored on nitrogen-doped hollow carbon spheres as cathode catalysts for Li–O2 batteries10.1039/C9NR03521D ↗
91. Facile synthesis of hierarchical porous Co3O4 nanoboxes as efficient cathode catalysts for Li–O2 batteries10.1039/C6TA01995A ↗
92. Single crystalline Co3O4 nanocrystals exposed with different crystal planes for Li-O2 batteries10.1038/srep05767 ↗
93. Facet-dependent electrocatalytic performance of Co3O4 for rechargeable Li–O2 battery10.1021/jp511363p ↗
94. Formation of NiCo2O4 rods over Co3O4 nanosheets as efficient catalyst for Li–O2 batteries and water splitting10.1016/j.jcat.2017.03.015 ↗
95. An open-structured matrix as oxygen cathode with high catalytic activity and Large Li2O2 accommodations for lithium–oxygen batteries10.1002/aenm.201800089 ↗
96. Tunable cationic vacancies of cobalt oxides for efficient electrocatalysis in Li–O2 batteries
97. Nanostructured conductive metal organic frameworks for sustainable low charge overpotentials in Li–air batteries10.1002/smll.202102902 ↗
98. Spin-state manipulation of two-dimensional metal-organic framework with enhanced metal-oxygen covalency for lithium-oxygen batteries10.1002/anie.202114293 ↗
99. Fabrication of superior single-atom catalysts toward diverse electrochemical reactions10.1002/smtd.201800497 ↗
100. Emerging multifunctional single-atom catalysts/nanozymes10.1021/acscentsci.0c00512 ↗