journal article·2010-03-26

Negative Thermal Expansion in Discotic Liquid Crystals of Nanographenes

C. Grigoriadis, N. Haase, H.‐J. Butt, K. Müllen, G. Floudas

Advanced Materials· Volume 22· Issue 12
Publisher page

Abstract

Hexa-peri-hexabenzocoronene derivatives show a record high negative volumetric thermal expansion coefficient within the crystalline phase. Responsible for the negative thermal expansion is the increase of the tilt angle and the improved packing of the discotic cores with temperature and this has implications in the design of organic electronic devices as well as in advanced nanocomposites with controlled thermal properties.
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Research context

OpenAlex topics: Thermal Expansion and Ionic Conductivity · Advanced Battery Materials and Technologies · Flame retardant materials and properties

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