journal article·2006-04-18

Spatially Confined Corner Defects Induce Chemical Functionality of TiO2 Nanorods

B. M. Rabatic, N. M. Dimitrijevic, R. E. Cook, Z. V. Saponjic, T. Rajh

Advanced Materials· Volume 18· Issue 8
Publisher page

Abstract

The atomic structure of anisotropic titanium dioxide nanoparticles is characterized by HRTEM to identify coordination defects at the tip surfaces of the nanorods (see figure). At the tip regions of the nanoparticles, the titanium metal–metal atom spacings extend between the (001) planes and demonstrate site-specific chemical reactivity towards surface modifiers. The observed reactivity of the nanorod tip is reminiscent of selectivity found in organic and biological self-organizing systems.
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Research context

OpenAlex topics: Quantum Dots Synthesis And Properties · Electronic and Structural Properties of Oxides · Molecular Junctions and Nanostructures

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