Characteristics, materials, and performance of Ru-containing oxide cathode materials for rechargeable batteries
Source abstract
Abstract
Li-rich Mn-based cathode materials have attracted extensive attention due to their remarkable energy density contributed by additional anionic redox. However, they always suffer from some undesired problems impeding their further commercialization such as irreversible oxygen loss, transition metal migration, sluggish kinetics and so on. Fortunately, the above issue can be relieved effectively when 3d metal Mn is replaced by 4d metal Ru. We focus on the recent progress of Ru-containing cathode materials and make a detailed summarization in this review. We attempt to combine and elucidate the relationship between oxygen and Ru redox. Subsequently, the up-to-date materials of Ru-based cathode materials for Li+/Na+ batteries are concluded systematically. Afterward, the effects of Ru are discussed in depth including enhancing the reversibility of anionic redox and structural stability, modulating the ratio between cationic and anionic redox, improving the kinetics of Li+/Na+, inhibiting the transition metal migration and so on. More importantly, the future designs of Ru-containing cathode materials are also proposed enlighteningly. We hope this review could inject some new perspectives to comprehend the layered oxides involving anionic redox and provide useful guidelines to achieve better Li+/Na+ rechargeable batteries.
Source: openalex_inverted_index · Quality: baseline
Research context
OpenAlex topics: Advancements in Battery Materials · Advanced Battery Materials and Technologies · Supercapacitor Materials and Fabrication
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (100+)
Show source-provided references
1. Recent progress in the emerging modification strategies for layered oxide cathodes toward practicable sodium ion batteries
2. Layered oxide cathodes for sodium-ion batteries: storage mechanism, electrochemistry, and techno-economics10.1021/acs.accounts.2c00690 ↗
3. Insights for understanding multiscale degradation of LiFePO4 cathodes10.1016/j.esci.2022.03.006 ↗
4. High-capacity electrode materials for rechargeable lithium batteries: Li3NbO4-based system with cation-disordered rocksalt structure10.1073/pnas.1504901112 ↗
5. Charge-compensation in 3d-transition-metal-oxide intercalation cathodes through the generation of localized electron holes on oxygen10.1038/nchem.2471 ↗
6. Exploring the bottlenecks of anionic redox in Li-rich layered sulfides10.1038/s41560-019-0493-0 ↗
7. Anionic redox in rechargeable batteries: mechanism, materials, and characterization10.1002/adfm.202303191 ↗
8. Fundamental understanding and practical challenges of anionic redox activity in Li-ion batteries10.1038/s41560-018-0097-0 ↗
9. Unified picture of anionic redox in Li/Na-ion batteries10.1038/s41563-019-0318-3 ↗
10. A mechanistic insight into the oxygen redox of Li-rich layered cathodes and their related electronic/atomic behaviors upon cycling10.1002/adma.202211965 ↗
11. Utilizing oxygen redox in layered cathode materials from multiscale perspective10.1002/aenm.202003227 ↗
12. Voltage decay of Li-rich layered oxides: mechanism, modification strategies, and perspectives
13. Understanding voltage hysteresis and decay during anionic redox reaction in layered transition metal oxide cathodes: a critical review10.1007/s12274-022-5003-1 ↗
14. Quantifying the capacity contributions during activation of Li2MnO310.1021/acsenergylett.9b02799 ↗
15. Dislocation and oxygen-release driven delithiation in Li2MnO310.1038/s41467-020-18285-z ↗
16. Direct observation of layered-to-spinel phase transformation in Li2MnO3 and the spinel structure stabilised after the activation process10.1039/C6TA11151C ↗
17. Charging mechanism of Li2MnO310.1021/acs.chemmater.9b04459 ↗
18. Structure and bonding in lithium ruthenate, Li2RuO310.1016/0022-4596(88)90357-X ↗
19. Regulating the potential of anion redox to reduce the voltage hysteresis of Li-rich cathode materials10.1021/jacs.2c11640 ↗
20. Reversible anionic redox chemistry in high-capacity layered-oxide electrodes10.1038/nmat3699 ↗
21. Towards controlling the reversibility of anionic redox in transition metal oxides for high-energy Li-ion positive electrodes10.1039/D0EE03765F ↗
22. Correlations between transition-metal chemistry, local structure, and global structure in Li2Ru0.5Mn0.5O3 investigated in a wide voltage window10.1021/acs.chemmater.7b02299 ↗
23. High performance Li2Ru1–yMnyO3 (0.2 ≤ y ≤ 0.8) cathode materials for rechargeable lithium-ion batteries: their understanding10.1021/cm400193m ↗
24. Effect of Ru substitution on the first charge–discharge cycle of lithium-rich layered oxides10.1039/C4TA05178E ↗
25. Synthesis, phase relation and electrical and electrochemical properties of ruthenium-substituted Li2MnO3 as a novel cathode material10.1016/j.jpowsour.2010.11.150 ↗
26. Lattice-tuned magnetism of Ru4+(4d4) ions in single crystals of the layered honeycomb ruthenates Li2RuO3 and Na2RuO310.1103/PhysRevB.90.161110 ↗
27. Double-hole-induced oxygen dimerization in transition metal oxides
28. Toward establishing electronic and phononic signatures of reversible lattice oxygen oxidation in lithium transition metal oxides for Li-ion batteries10.1021/acs.chemmater.0c00245 ↗
29. Distinct oxygen redox activities in Li2MO3 (M = Mn, Ru, Ir)10.1021/acsenergylett.1c01101 ↗
30. Layered Na2RuO3 as a cathode material for Na-ion batteries10.1016/j.elecom.2013.04.011 ↗
31. Reversible anionic redox activity in Na3RuO4 cathodes: a prototype Na-rich layered oxide10.1039/C7EE03554C ↗
32. Stabilizing reversible oxygen redox chemistry in layered oxides for sodium-ion batteries10.1002/aenm.201903785 ↗
33. Boosting reversible anionic redox reaction with Li/Cu dual honeycomb centers10.1016/j.esci.2023.100159 ↗
34. Unraveling anionic redox for sodium layered oxide cathodes: breakthroughs and perspectives10.1002/adma.202106171 ↗
35. Challenges and recent advances in high capacity Li-rich cathode materials for high energy density lithium-ion batteries
36. A review on progress of lithium-rich manganese-based cathodes for lithium ion batteries10.1016/j.jpowsour.2020.229362 ↗
37. Synthesis, structure, electrochemical mechanisms, and atmospheric stability of Mn-based layered oxide cathodes for sodium ion batteries10.1021/accountsmr.2c00058 ↗
38. Spinel/post-spinel engineering on layered oxide cathodes for sodium-ion batteries10.1016/j.esci.2021.10.003 ↗
39. Manganese oxidation as the origin of the anomalous capacity of Mn-containing Li-excess cathode materials10.1038/s41560-019-0439-6 ↗
40. The origin of electrochemical activity in Li2MnO310.1039/b207945c ↗
41. Demonstrating oxygen loss and associated structural reorganization in the lithium battery cathode Li[Ni0.2Li0.2Mn0.6]O210.1021/ja062027+ ↗
42. Detailed studies of a high-capacity electrode material for rechargeable batteries, Li2MnO3-LiCo1/3Ni1/3Mn1/3O210.1021/ja108588y ↗
43. Lithium metal rechargeable cells using Li2MnO3 as the positive electrode10.1016/S0378-7753(99)00066-X ↗
44. Cycling mechanism of Li2MnO3: Li–CO2 batteries and commonality on oxygen redox in cathode materials10.1016/j.joule.2021.02.004 ↗
45. Direct observation of reversible oxygen anion redox reaction in Li-rich manganese oxide, Li2MnO3, studied by soft X-ray absorption spectroscopy10.1039/C6TA00174B ↗
46. Li-Rich Mn–Mg layered oxide as a novel Ni-/Co-free cathode10.1002/adfm.202204354 ↗
47. Advanced characterizations and measurements for sodium-ion batteries with NASICON-type cathode materials10.1016/j.esci.2021.12.008 ↗
48. Requirements for reversible extra-capacity in Li-rich layered oxides for Li-ion batteries10.1039/C6EE02328B ↗
49. Decoupling cationic–anionic redox processes in a model Li-rich cathode via operando X-ray absorption spectroscopy10.1021/acs.chemmater.7b03434 ↗
50. Mechanism of electrochemical activity in Li2MnO310.1021/cm030047u ↗
51. Material design of high-capacity Li-rich layered-oxide electrodes: Li2MnO3 and beyond10.1039/C7EE01782K ↗
52. X-ray photoemission spectroscopy study of cationic and anionic redox processes in high-capacity Li-ion battery layered-oxide electrodes10.1021/acs.jpcc.5b10475 ↗
53. Understanding the roles of anionic redox and oxygen release during electrochemical cycling of lithium-rich layered Li4FeSbO610.1021/jacs.5b01424 ↗
54. Charge transfer band gap as an indicator of hysteresis in Li-disordered rock salt cathodes for Li-ion batteries10.1021/jacs.8b11413 ↗
55. Origin of stabilization and destabilization in solid-state redox reaction of oxide ions for lithium-ion batteries10.1038/ncomms13814 ↗
56. Capturing dynamic ligand-to-metal charge transfer with a long-lived cationic intermediate for anionic redox10.1038/s41563-022-01278-2 ↗
57. Electrostatic interactions versus second order Jahn–Teller distortion as the source of structural diversity in Li3MO4 compounds (M = Ru, Nb, Sb and Ta)10.1021/acs.chemmater.7b04117 ↗
58. Evolutionary programming techniques for predicting inorganic crystal structures10.1039/jm9950501269 ↗
59. Approaching the limits of cationic and anionic electrochemical activity with the Li-rich layered rocksalt Li3IrO410.1038/s41560-017-0042-7 ↗
60. Structural classification and properties of the layered oxides
61. 17O NMR spectroscopy in lithium-ion battery cathode materials: challenges and interpretation10.1021/jacs.2c02927 ↗
62. Characterizing the structure and phase transition of Li2RuO3 using variable-temperature 17O and 7Li NMR spectroscopy10.1021/acs.chemmater.8b05178 ↗
63. Structure and lithium deintercalation of Li2RuO310.1016/0167-2738(95)00135-S ↗
64. Physical properties of the de-lithiated Li2-xRuO3 with the layered structure10.1016/0167-2738(96)00194-4 ↗
65. Origin of voltage decay in high-capacity layered oxide electrodes10.1038/nmat4137 ↗
66. The electrochemical behavior of xLiNiO2·(1−x)Li2RuO3 and Li2Ru1−yZryO3 electrodes in lithium cells10.1016/S0378-7753(03)00184-8 ↗
67. Ion-exchange: a promising strategy to design Li-rich and Li-excess layered cathode materials for Li-ion batteries
68. Fundamentals of ion-exchange synthesis and its implications in layered oxide cathodes: recent advances and perspective10.1002/aenm.202300125 ↗
69. Inhibition of oxygen dimerization by local symmetry tuning in Li-rich layered oxides for improved stability10.1038/s41467-020-18423-7 ↗
70. Triggering and stabilizing oxygen redox chemistry in layered Li[Na1/3Ru2/3]O2 enabled by stable Li–O–Na configuration10.1021/acsenergylett.2c01072 ↗
71. Understanding the stability for Li-rich layered oxide Li2RuO3 cathode10.1002/adfm.201504836 ↗
72. Elucidating anionic oxygen activity in lithium-rich layered oxides10.1038/s41467-018-03403-9 ↗
73. Exploring the influence of iron substitution in lithium rich layered oxides Li2Ru1−xFexO3: triggering the anionic redox reaction10.1039/C7TA04194B ↗
74. Chromium doped Li2RuO3 as a positive electrode with superior electrochemical performance for lithium ion batteries10.1039/C7CC07545F ↗
75. Improving the electrochemical performance of Li2RuO3 through chemical substitution: a case study of (x)LiCoO2-(1-x)Li2RuO3 solid solution (x≤0.4)10.1002/celc.201902059 ↗
76. XRD and XAFS study on structure and cation valence state of layered ruthenium oxide electrodes, Li2RuO3 and Li2Mn0.4Ru0.6O3, upon electrochemical cycling10.1016/j.ssi.2015.09.025 ↗
77. Irreversible anion oxidation leads to dynamic charge compensation in the Ru-poor, Li-rich cathode Li2Ru0.3Mn0.7O310.1021/acsenergylett.2c02537 ↗
78. The effect of electrochemically inactive Ti substituted for Ru in Li2Ru1-xTixO3 on structure and electrochemical performance10.1016/j.jechem.2020.12.037 ↗
79. Lithium rich composition of Li2RuO3 and Li2Ru1-xIrxO3 layered materials as Li-ion battery cathode10.1149/2.030406jes ↗
80. Selective anionic redox and suppressed structural disordering enabling high-energy and long-life Li-rich layered-oxide cathode10.1002/aenm.202102311 ↗
81. Tuning the reversibility of oxygen redox in lithium-rich layered oxides10.1021/acs.chemmater.6b04743 ↗
82. Structural and magnetic properties of Li3RuO410.1039/b305220f ↗
83. Definition of redox centers in reactions of lithium intercalation in Li3RuO4 polymorphs10.1021/jacs.9b12438 ↗
84. A new type of Li-rich rock-salt oxide Li2Ni1/3Ru2/3O3 with reversible anionic redox chemistry
85. Layered-rocksalt intergrown cathode for high-capacity zero-strain battery operation10.1038/s41467-021-22527-z ↗
86. The Li3RuyNb1–yO4 (0 ≤ y ≤ 1) system: structural diversity and Li insertion and extraction capabilities10.1021/acs.chemmater.7b01511 ↗
87. Competition between metal dissolution and gas release in Li-Rich Li3RuyIr1–yO4 model compounds showing anionic redox10.1021/acs.chemmater.8b02955 ↗
88. Crystal structures, dimorphism and lithium mobility of Li7MO6 (M = Bi, Ru, Os)10.1002/zaac.200500231 ↗
89. Li7RuO6: as a 4d Heisenberg frustrated magnet10.1143/JPSJ.79.064705 ↗
90. Access to Ru(IV)–Ru(V) and Ru(V)–Ru(VI) redox in layered Li7RuO6 via intercalation reactions10.1021/acs.chemmater.2c00043 ↗
91. Sodium transition metal oxides: the preferred cathode choice for future sodium-ion batteries?10.1039/D0EE02997A ↗
92. Synergetic anion-cation co-doping in Na0.44MnO2 boosting a high-stability and improved-kinetics cathode for sodium ion battery
93. Precipitate-stabilized surface enabling high-performance Na0.67Ni0.33-xMn0.67ZnxO2 for sodium-ion battery10.1016/j.esci.2022.08.003 ↗
94. Heterostructure engineering in electrode materials for sodium ion batteries: recent progress and perspectives10.1016/j.esci.2023.100139 ↗
95. Structure-induced reversible anionic redox activity in Na layered oxide cathode10.1016/j.joule.2017.10.008 ↗
96. Oxygen redox chemistry without excess alkali-metal ions in Na2/3[Mg0.28Mn0.72]O210.1038/nchem.2923 ↗
97. Exceptionally highly stable cycling performance and facile oxygen-redox of manganese-based cathode materials for rechargeable sodium batteries10.1016/j.nanoen.2019.02.042 ↗
98. Both cationic and anionic redox chemistry in a P2-type sodium layered oxide10.1016/j.nanoen.2020.104474 ↗
99. Anionic redox reaction triggered by trivalent Al3+ in P3-Na0.65Mn0.5Al0.5O210.1039/D1CC00373A ↗
100. Coulombically-stabilized oxygen hole polarons enable fully reversible oxygen redox10.1039/D1EE01037A ↗