journal article·2026-06Open access

Thermoplastic tensile specimens under one-sided thermal load – temperature evaluation and failure after cooling

Alexander Hofmann, Benjamin Schaufelberger, Stefan Reich, Marcel Goesmann, Philipp Hahn, Pascal Matura, Michael May

Abstract

A thorough understanding of polymer behavior under asymmetric thermal loading is a prerequisite for assessing the fire resistance of polymer structures. Yet, despite the widespread use of both fiber-reinforced and unfilled thermoplastics, their performance under such conditions remains insufficiently studied. In the present study polyoxymethylene (POM) tensile test specimens are exemplarily studied, the high thermal load is applied by a laser. Whereas on the irradiated front side temperatures considerably above the melting temperature occurred, temperatures on the back side were below. Quasistatic uniaxial tensile tests at room temperature after cooling showed that the elongation at break is strongly reduced by the irradiation, for stiffness and strength only a minor decrease could be observed. The transient temperature field inside the specimens was simulated by finite element analysis. This temperature was used to introduce a temperature dependent damage thickness which describes the thickness of the zone assumed to be irreversibly damaged by the thermal load. Based on this, an empirical model for the decrease of elongation at break of the investigated POM specimens is proposed.
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Research context

OpenAlex topics: Mechanical Behavior of Composites · High Temperature Alloys and Creep · Fire effects on concrete materials

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (65)

Show source-provided references
1. Experimental thermal runaway degradation and residual performance of fiber-reinforced PEEK and PPS composites for battery enclosure applications10.1016/j.engfailanal.2025.110430 ↗
2. A review of lithium ion battery failure mechanisms and fire prevention strategies10.1016/j.pecs.2019.03.002 ↗
3. A detailed simulation model to evaluate the crash safety of a Li-ion pouch battery cell
4. A review of safety-focused mechanical modeling of commercial lithium-ion batteries10.1016/j.jpowsour.2017.12.034 ↗
5. Towards separator safety of lithium-ion batteries: a review10.1039/D3QM00951C ↗
6. Safety focused modeling of lithium-ion batteries: a review10.1016/j.jpowsour.2015.11.100 ↗
7. Failure and constitutive behavior of a Li-ion pouch cell under mechanical loading10.1016/j.powera.2025.100178 ↗
8. Fire behaviour of composite laminates10.1016/S1359-835X(00)00015-4 ↗
9. Modelling the tension and compression strengths of polymer laminates in fire10.1016/j.compscitech.2006.07.038 ↗
10. Tensile and compressive properties of FRP composites with localised fire damage10.1023/A:1020204913612 ↗
11. Mechanical properties of fire-damaged glass-reinforced phenolic composites10.1002/1099-1018(200003/04)24:2<67::AID-FAM720>3.0.CO;2-0 ↗
12. Post-fire mechanical properties of glass-reinforced polyester composites10.1016/S0266-3538(00)00204-9 ↗
13. Post-fire mechanical properties of marine polymer composites10.1016/S0263-8223(00)00043-X ↗
14. Review of fire structural modelling of polymer composites10.1016/j.compositesa.2009.09.001 ↗
15. The Integrity of Polymer Composites during and after Fire10.1177/0021998304042733 ↗
16. A model for the thermal performance of thick composite laminates in hydrocarbon fires10.2516/ogst:1995007 ↗
17. A one‐dimensional finite element simulation for the fire‐performance of GRP panels for offshore structures10.1108/09615539710170781 ↗
18. Modeling of mechanical response of FRP composites in fire, Compos. - a
19. Laser Interactions with Organic/Polymer Materials
20. Numerical modeling and characterization of the laser–matter interaction during high-power continuous wave laser perforation of thin metal plates10.2351/1.4906467 ↗
21. Heat transfer in semi-transparent materials during laser interaction10.1016/j.jmatprotec.2004.04.380 ↗
22. Through-transmission laser welding of polymers – temperature field modeling and infrared investigation10.1016/j.infrared.2007.02.003 ↗
23. Biasi · 2014
24. Thermal and damage analysis of laser-induced decomposition within carbon/epoxy composite laminates10.1177/0734904116653617 ↗
25. M. Ross, D. Pope, Development of a finite element model of high energy laser-material interaction, 13th European LS-DYNA Conference, Ulm, Germany, 2021. https://www.dynalook.com/conferences/13th-european-ls-dyna-conference-2021/simulation-methods/ross_dstl.pdf/view, 2025 (accessed 02 June 2025).
26. Study of the laser-material interaction for innovative hybrid structures: Thermo-mechanical characterization of polyethylene-based polymers10.1016/j.polymertesting.2023.107947 ↗
27. Numerical modelling of thermal decomposition processes and associated damage in carbon fibre composites10.1088/0022-3727/47/38/385301 ↗
28. Experimental and numerical analysis of damage mechanisms for carbon fiber-reinforced polymer composites subjected to lightning strikes10.1016/j.engfailanal.2020.104894 ↗
29. Numerical modeling and experimental validation of heat and mass transfer within decomposing carbon fibers/epoxy resin composite laminates10.1016/j.ijthermalsci.2024.109040 ↗
30. Approaches to understand and predict the influence of rapid heat-up on degradation and strength of carbon fibre polymer matrix composites10.1177/0021998316671184 ↗
31. Measurement of kinetics and thermodynamics of the thermal degradation for non-charring polymers10.1016/j.combustflame.2013.02.012 ↗
32. Thermal degradation behaviour of poly(oxymethylene): 1. Degradation and stabilizer consumption10.1016/j.polymdegradstab.2004.03.011 ↗
33. Modeling of the kinetics of polyoxymethylene decomposition under oxidative and non-oxidative conditions10.3390/ma14092281 ↗
34. Analysis of thermal degradation kinetics of POM under inert and oxidizing atmospheres and combustion characteristics with flame retardant effects10.3390/polym15102286 ↗
35. International Organization for Standardization, ISO 20753:2023-11. Plastics - Test specimens (2023).
36. International Organization for Standardization, ISO 8256:2023-11. Plastics - Determination of tensile-impact strength (2023).
37. International Organzation for Standardization, ISO 11146-1:2021-11. Lasers and laser-related equipment - Test methods for laser beam widths, divergence angles and beam propagation ratios - Part 1: Stigmatic and simple astigmatic beams (2021).
38. Numerical investigation of the influence of thermal runaway modelling on car park fire hazard and application to a Lithium-ion Manganese Oxide battery10.1016/j.firesaf.2024.104284 ↗
39. Fire performance of short and long glass fiber polypropylene composites for electric vehicle battery enclosures
40. Heat flux from flames to vertical surfaces10.1007/BF01040003 ↗
41. Development of fire-retarded materials - interpretation of cone calorimeter data10.1002/fam.949 ↗
42. Composite structure failure analysis post Lithium-Ion battery fire10.1016/j.engfailanal.2024.108163 ↗
43. Effect of a plate obstacle on fire behavior of 18650 lithium ion battery: an experimental study10.1016/j.est.2022.105283 ↗
44. International Organization for Standardization, ISO 527-1:2019-07. Plastics - Determination of tensile properties - Part 1: General principles (2019).
45. Anderson · Encycl. Polym. Sci. Technol. · 1970 · 13 · 764
46. Brandrup · 1975
47. Determination of thermal conductivity by differential scanning calorimetry10.1016/0040-6031(79)87116-6 ↗
48. Thermal conductivity and tribological properties of POM-Cu composites10.1002/pen.21750 ↗
49. Thermophysical, rheological and morphological properties of polyoxymethylene polymer composite for additive technologies10.1007/s11182-018-1492-5 ↗
50. Kline · Tech. Methods Polym. Eval. · 1970 · 2 · 247
51. Heat capacity and other thermodynamic properties of linear macromolecules. III. Polyoxides
52. Heat capacities of liquids linear aliphatic polyoxides10.1002/pol.1985.180230818 ↗
53. Thermal conductivity of polymer melts10.1016/0040-6031(90)80170-4 ↗
54. Structure and properties of highly oriented polyoxymethylene/multi-walled carbon nanotube composites produced by hot stretching10.1016/j.compscitech.2011.05.011 ↗
55. Perry · 1963
56. A non-steady method for determination of thermal diffusivity and thermal conductivity of poorly conductive solids10.1080/00986449108910867 ↗
57. Comparative study on the mechanical, tribological, and thermal properties of POM composites filled with different PTFE10.1177/0892705720932620 ↗
58. Nonisothermal crystallization kinetics of polyoxymethylene/montmorillonite nanocomposite10.1002/app.2076 ↗
59. Investigation on the crystallization behaviors of polyoxymethylene with a small amount of ionic liquid10.3390/nano9020206 ↗
60. A study of the controlled degradation of polypropylene containing pro-oxidant agents10.1186/2193-1801-2-623 ↗
61. Polyhedral oligomeric silsesquioxanes as modifiers of polyoxymethylene structure10.1063/1.4937291 ↗
62. POM mechanical properties
63. Mechanism of degradation induced embrittlement in polyethylene10.1016/j.polymdegradstab.2006.11.012 ↗
64. Review: Degradation-induced embrittlement in semi-crystalline polymers having their amorphous phase in rubbery state10.1007/s10853-008-3005-3 ↗
65. Thermooxidative aging of polyoxymethylene, Part 2: Embrittlement mechanisms10.1002/app.29126 ↗