Superdurable Full‐Life Superhydrophobic Composite Block

Abstract Superhydrophobic materials are attractive for industrial development but plagued by poor mechanical stability. Herein, a superdurable full‐life superhydrophobic composite block is designed and fabricated by embedding near‐zero contractive superhydrophobic silica aerogel into a rigid iron‐nickel foam structured similarly to a regular dodecahedron. The synergistic protection afforded by these materials ensures superrobust mechanical stability for the composite block, which features a high compressive strength of up to ≈7.4 MPa, and ultralow Taber abrasion of down to ≈0.567 mm after withstanding 50 000 cycles, and highly efficient water harvesting capability of up to ≈3114.3 mg min⁻¹ cm⁻² at a supercooling degree of 40 K. This robust material system provides a novel strategy to design superhydrophobic materials capable of withstanding extreme conditions, including high temperature, humidity, pressure, and abrasion.