Versatile Nitrogen‐Centered Organic Redox‐Active Materials for Alkali Metal‐Ion Batteries

Abstract Versatile nitrogen‐centered organic redox‐active molecules have gained significant attention in alkali metal‐ion batteries (AMIBs) due to their low cost, low toxicity, and ease of preparation. Specially, their multiple reaction categories (anion/cation insertion types of reaction) and higher operating voltage, when compared to traditional conjugated carbonyl materials, underscore their promising prospects. However, the high solubility of nitrogen‐centered redox active materials in organic electrolyte and their low electronic conductivity contribute to inferior cycling performance, sluggish reaction kinetics, and limited rate capability. This review provides a detailed overview of nitrogen‐centered redox‐active materials, encompassing their redox chemistry, solutions to overcome shortcomings, characterization of charge storage mechanisms, and recent progress. Additionally, prospects and directions are proposed for future investigations. It is anticipated that this review will stimulate further exploration of underlying mechanisms and interface chemistry through in situ characterization techniques, thereby promoting the practical application of nitrogen‐centered redox‐active materials in AMIBs.