Metalloligand Nickel Bis(Dithiolene) Based Metal–Organic Frameworks for Efficient Photocurrent and Photothermal Conversion

Nickel bis(dithiolene) complexes are strong sunlight absorbers with high thermal- and photostability and are nonluminescent, resulting in remarkable photothermal properties. Nevertheless, nickel-bis(dithiolene)-based metal–organic frameworks (MOFs) have rarely been reported as photothermal and photocurrent agents. Herein, nickel-bis(dithiolene-dibenzoic acid) [Ni(C 2 S 2 (C 6 H 4 COOH) 2 ) 2 ], as a new functional redox-reversible “non-innocent” metalloligand, was innovatively assembled into two MOFs, [Zn 2 {Ni(C 2 S 2 (C 6 H 4 COO) 2 ) 2 }(H 2 O) 2 ]·2DMF and [Cd 2 {Ni(C 2 S 2 (C 6 H 4 COO) 2 ) 2 }(H 2 O) 2 ]·2DMF ( 1 and 2, DMF = N, N -dimethylformamide). Under one-sun illumination (0.1 W cm –2, 300–2500 nm), the temperature of the MOFs sharply increased to 69.6 and 69.3 °C from room temperature in 300 s, concomitant with induced photocurrents of 7.0 and 6.5 μA for 1 and 2 . The considerable performance is due to charge transfer, as revealed by cyclic voltammetry (CV) and solid-state UV/vis–NIR spectroscopy. This study not only provides insights into the development of photothermal and photoconductivity materials but also paves the way for designing functional materials with appealing applications.