Bifunctional Catalysts for CO₂ Reduction and O₂ Evolution: A Pivotal for Aqueous Rechargeable Zn−CO₂ Batteries

Abstract The quest for the advancement of green energy storage technologies and reduction of carbon footprint is determinedly rising toward carbon neutrality. Aqueous rechargeable Zn–CO₂ batteries (ARZCBs) hold the great potential to encounter both the targets simultaneously, i.e., green energy storage and CO₂ conversion to value‐added chemicals/fuels. The major descriptor of ARZCBs efficiency is allied with the reactions occurring at cathode during discharging (CO₂ reduction) and charging (O₂ evolution) which own different fundamental mechanisms and hence mandate the employment of two different catalysts. This presents an overall complex and expensive battery system which requires a concrete solution, while the development and application of a bifunctional cathode catalyst toward both reactions could reduce the complexity and cost and thus can be a pivotal for ARZCBs. However, despite the increasing research interest and ongoing research, a systematic evaluation of bifunctional catalysts is rarely reported. In this review, the need of bifunctional cathode catalysts for ARZCBs and associated challenges with strategies have been critically assessed. A detailed progress examination and understanding toward designing of bifunctional catalyst for ARZCBs have been provided. This review will enlighten the future research approaching boosted performance of ARZCBs through the development of efficient bifunctional cathode catalysts.