journal article·2024-05Open access

Mechanically Robust Self‐Organized Crack‐Free Nanocellular Graphene with Outstanding Electrochemical Properties in Sodium Ion Battery

Wong‐Young Park, Jiuhui Han, Jongun Moon, Soo‐Hyun Joo, Takeshi Wada, Yuji Ichikawa, Kazuhiro Ogawa, Hyoung Seop Kim, Mingwei Chen, Hidemi Kato

Advanced Materials· Volume 36· Issue 21

Abstract

Abstract Crack‐free nanocellular graphenes are attractive materials with extraordinary mechanical and electrochemical properties, but their homogeneous synthesis on the centimeter scale is challenging. Here, a strong nanocellular graphene film achieved by the self‐organization of carbon atoms using liquid metal dealloying and employing a defect‐free amorphous precursor is reported. This study demonstrates that a Bi melt strongly catalyzes the self‐structuring of graphene layers at low processing temperatures. The robust nanoarchitectured graphene displays a high‐genus seamless framework and exhibits remarkable tensile strength (34.8 MPa) and high electrical conductivity (1.6 × 104 S m−1). This unique material has excellent potential for flexible and high‐rate sodium‐ion battery applications.
Source: crossref · Quality: baseline

Research context

OpenAlex topics: Supercapacitor Materials and Fabrication · Graphene research and applications · Advancements in Battery Materials

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Institute for Materials Research Tohoku University Katahira 2‐1‐1 Sendai 980‐8577 Japan

Tianjin Key Laboratory of Advanced Functional Porous Materials Institute for New Energy Materials and Low‐Carbon Technologies Tianjin University of Technology 391 Binshui West Road Tianjin 300384 China

Frontier Research Institute for Interdisciplinary Sciences Tohoku University 6‐3 Aoba Sendai 980‐8578 Japan

Department of Materials Science and Engineering Pohang University of Science and Technology 77 Cheongam‐Ro Pohang 37673 Republic of Korea

Division of Advanced Materials Engineering Center for Advanced Powder Materials and Parts Kongju National University 1223‐24 Cheonan‐daero Cheonan 31080 Republic of Korea

Department of Materials Science and Engineering Dankook University 119 Dandae‐ro Cheonan 31116 Republic of Korea

Fracture and Reliability Research Institute (FRI) Tohoku University 6‐6‐11 Aoba Sendai 980‐8579 Japan

Advanced Institute for Materials Research (WPI‐AIMR) Tohoku University Katahira 2‐1‐1 Sendai 980‐8577 Japan

Institute for Convergence Research and Education in Advanced Technology Yonsei University Yonsei‐ro 50 Seoul 03722 Republic of Korea

Department of Materials Science and Engineering Johns Hopkins University 3400 N. Charles Street Baltimore MD 21218‐2681 USA

Funding

National Research Foundation of Korea · National Key Research and Development Program of China · National Natural Science Foundation of China

References (71)

Show source-provided references
1. 10.1021/nn300179n10.1021/nn300179n ↗
2. 10.1002/adma.20180100110.1002/adma.201801001 ↗
3. 10.1038/s41563-021-01033-z10.1038/s41563-021-01033-z ↗
4. 10.1002/anie.20170068410.1002/anie.201700684 ↗
5. 10.1016/j.actamat.2011.08.02510.1016/j.actamat.2011.08.025 ↗
6. 10.1002/smll.20190284210.1002/smll.201902842 ↗
7. 10.1002/adma.20170185010.1002/adma.201701850 ↗
8. 10.1016/S1359-6454(00)00379-710.1016/S1359-6454(00)00379-7 ↗
9. 10.1002/adem.20180002910.1002/adem.201800029 ↗
10. 10.1016/j.pmatsci.2011.01.00510.1016/j.pmatsci.2011.01.005 ↗
11. 10.1038/ncomms874810.1038/ncomms8748 ↗
12. 10.1038/s41563-021-01039-710.1038/s41563-021-01039-7 ↗
13. 10.1126/science.115887710.1126/science.1158877 ↗
14. 10.1016/j.pmatsci.2017.07.00410.1016/j.pmatsci.2017.07.004 ↗
15. 10.1038/nphoton.2012.26210.1038/nphoton.2012.262 ↗
16. 10.1002/adma.20150615710.1002/adma.201506157 ↗
17. 10.1038/ncomms532810.1038/ncomms5328 ↗
18. 10.1002/adma.20210875010.1002/adma.202108750 ↗
19. 10.1016/j.carbon.2019.11.04710.1016/j.carbon.2019.11.047 ↗
20. 10.1016/j.matlet.2011.01.05410.1016/j.matlet.2011.01.054 ↗
21. 10.1002/adma.20190616010.1002/adma.201906160 ↗
22. 10.1038/ncomms988710.1038/ncomms9887 ↗
23. 10.1016/j.jmst.2021.07.02310.1016/j.jmst.2021.07.023 ↗
24. 10.1007/s11661-008-9625-z10.1007/s11661-008-9625-z ↗
25. 10.1021/nl201699j10.1021/nl201699j ↗
26. 10.1021/nl061702a10.1021/nl061702a ↗
27. 10.1063/1.482106610.1063/1.4821066 ↗
28. 10.1016/0008-6223(78)90077-510.1016/0008-6223(78)90077-5 ↗
29. 10.1126/science.117124510.1126/science.1171245 ↗
30. 10.1063/1.298258510.1063/1.2982585 ↗
31. 10.1038/s41467-018-07942-z10.1038/s41467-018-07942-z ↗
32. 10.1016/j.xcrp.2023.10128310.1016/j.xcrp.2023.101283 ↗
33. 10.1088/0957-4484/24/36/36560210.1088/0957-4484/24/36/365602 ↗
34. 10.1021/jp111962k10.1021/jp111962k ↗
35. 10.1126/science.aao502310.1126/science.aao5023 ↗
36. 10.1126/science.adh887210.1126/science.adh8872 ↗
37. 10.1039/c2ra20549a10.1039/c2ra20549a ↗
38. 10.1016/j.compositesa.2013.06.00810.1016/j.compositesa.2013.06.008 ↗
39. 10.1002/adma.20190118610.1002/adma.201901186 ↗
40. 10.1038/ncomms390510.1038/ncomms3905 ↗
41. 10.1021/ja107229910.1021/ja1072299 ↗
42. 10.1021/nn101187z10.1021/nn101187z ↗
43. 10.1002/adma.20120049110.1002/adma.201200491 ↗
44. 10.1039/c2cc33979j10.1039/c2cc33979j ↗
45. 10.1002/anie.20100027010.1002/anie.201000270 ↗
46. 10.1021/jz200223x10.1021/jz200223x ↗
47. 10.1021/nn402272u10.1021/nn402272u ↗
48. 10.1039/c2nr32157b10.1039/c2nr32157b ↗
49. 10.1038/nmat300110.1038/nmat3001 ↗
50. 10.1021/acs.nanolett.5b0392310.1021/acs.nanolett.5b03923 ↗
51. 10.1021/acs.langmuir.8b0400710.1021/acs.langmuir.8b04007 ↗
52. 10.1021/nn302177210.1021/nn3021772 ↗
53. 10.1002/anie.20120655410.1002/anie.201206554 ↗
54. 10.1021/acsnano.7b0198710.1021/acsnano.7b01987 ↗
55. 10.1126/sciadv.aat695110.1126/sciadv.aat6951 ↗
56. 10.1002/adma.20150268210.1002/adma.201502682 ↗
57. 10.1038/ncomms225110.1038/ncomms2251 ↗
58. 10.1038/srep0211710.1038/srep02117 ↗
59. 10.1002/adma.20120457610.1002/adma.201204576 ↗
60. 10.1016/S1359-6454(03)00441-510.1016/S1359-6454(03)00441-5 ↗
61. 10.1126/science.125229110.1126/science.1252291 ↗
62. 10.1098/rspa.2010.021510.1098/rspa.2010.0215 ↗
63. 10.1073/pnas.160247311310.1073/pnas.1602473113 ↗
64. 10.1002/aenm.20160151910.1002/aenm.201601519 ↗
65. 10.1002/adfm.20140298410.1002/adfm.201402984 ↗
66. 10.1002/anie.20140373410.1002/anie.201403734 ↗
67. 10.1039/C5EE02051D10.1039/C5EE02051D ↗
68. 10.1039/C7EE00546F10.1039/C7EE00546F ↗
69. 10.1016/j.jpowsour.2015.05.11610.1016/j.jpowsour.2015.05.116 ↗
70. 10.1021/acs.nanolett.5b0418710.1021/acs.nanolett.5b04187 ↗
71. Ichikawa Y. · Proc. Int. Ther. Spray Conf. · 2017 · 1 · 328