1D Magnetic MX3 Single‐Chains (M = Cr, V and X = Cl, Br, I)
Source abstract
Abstract
Abstract Magnetic materials in reduced dimensions are not only excellent platforms for fundamental studies of magnetism, but they play crucial roles in technological advances. The discovery of intrinsic magnetism in monolayer 2D van der Waals systems has sparked enormous interest, but the single‐chain limit of 1D magnetic van der Waals materials has been largely unexplored. This paper reports on a family of 1D magnetic van der Waals materials with composition MX3 (M = Cr, V, and X = Cl, Br, I), prepared in fully‐isolated fashion within the protective cores of carbon nanotubes. Atomic‐resolution scanning transmission electron microscopy identifies unique structures that differ from the well‐known 2D honeycomb lattice MX3 structure. Density functional theory calculations reveal charge‐driven reversible magnetic phase transitions.
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Research context
OpenAlex topics: Graphene research and applications · MXene and MAX Phase Materials · 2D Materials and Applications
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Department of Physics University of California at Berkeley Berkeley CA 94720 USA
Materials Sciences Division Lawrence Berkeley National Laboratory Berkeley CA 94720 USA
Department of Physics Yonsei University Seoul 03722 South Korea
Center for Nanomedicine Institute for Basic Science Seoul 03722 South Korea
National Center for Electron Microscopy, The Molecular Foundry Lawrence Berkeley National Laboratory Berkeley CA 94720 USA
Kavli Energy NanoSciences Institute University of California at Berkeley Berkeley CA 94720 USA
Funding
National Research Foundation of Korea · Korea Research Institute of Standards and Science · Institute for Basic Science
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