journal article·2023-02

Piezoelectric 1T Phase MoSe2 Nanoflowers and Crystallographically Textured Electrodes for Enhanced Low‐Temperature Zinc‐Ion Storage

Yihui Li, Xingfang Dong, Zewen Xu, Menglei Wang, Ruofei Wang, Juan Xie, Yangjian Ding, Pengcheng Su, Chengying Jiang, Xingmin Zhang, Liyu Wei, Jing‐Feng Li, Zhaoqiang Chu, Jingyu Sun, Cheng Huang

Advanced Materials· Volume 35· Issue 6
Publisher page

Abstract

Abstract Transition metal dichalcogenides (TMDs) are regarded as promising cathode materials for zinc‐ion storage owing to their large interlayer spacings. However, their capabilities are still limited by sluggish kinetics and inferior conductivities. In this study, a facile one‐pot solvothermal method is exploited to vertically plant piezoelectric 1T MoSe2 nanoflowers on carbon cloth (CC) to fabricate crystallographically textured electrodes. The self‐built‐in electric field owing to the intrinsic piezoelectricity during the intercalation/deintercalation processes can serve as an additional piezo‐electrochemical coupling accelerator to enhance the migration of Zn2+. Moreover, the expanded interlayer distance (9–10 Å), overall high hydrophilicity, and conductivity of the 1T phase MoSe2 also promoted the kinetics. These advantages endow the tailored 1T MoSe2/CC nanopiezocomposite with feasible Zn2+ diffusion and desirable electrochemical performances at room and low temperatures. Moreover, 1T MoSe2/CC‐based quasi‐solid‐state zinc‐ion batteries are constructed to evaluate the potential of the proposed material in low‐temperature flexible energy storage devices. This work expounds the positive effect of intrinsic piezoelectricity of TMDs on Zn2+ migration and further explores the availabilities of TMDs in low‐temperature wearable energy‐storage devices.
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Research context

OpenAlex topics: Advanced battery technologies research · Supercapacitor Materials and Fabrication · Advancements in Battery Materials

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Volta and DiPole Materials Labs College of Energy Soochow Institute for Energy and Materials InnovationS (SIEMIS) Soochow Innovation Consortium for Intelligent Fibers and Wearable Technologies Key Laboratory of Advanced Carbon Materials and Wearable Energy Technologies of Jiangsu Province Key Laboratory of Core Technology of High Specific Energy Battery and Key Materials for Petroleum and Chemical Industry Soochow University 688 Moye Road Suzhou 215006 P. R. China

High Density Materials Technology Center for Flexible Hybrid Electronics Suzhou Institute of Electronic Functional Materials Technology Suzhou Industrial Technology Research Institute Suzhou 215151 P. R. China

College of Underwater Acoustic Engineering Harbin Engineering University Harbin 150001 P. R. China

School of Materials Science and Engineering Jiangsu University Zhenjiang 212013 P. R. China

School of Textile Garment and Design Changshu Institute of Technology Changshu 215500 P. R. China

Shanghai Synchrotron Radiation Facility Shanghai Advanced Research Institute Shanghai Institute of Applied Physics Chinese Academy of Sciences Shanghai 201204 P. R. China

State Key Laboratory of New Ceramics and Fine Processing School of Materials Science and Engineering Tsinghua University Beijing 100084 P. R. China

Funding

National Key Research and Development Program of China · National Natural Science Foundation of China

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