Design and construction of few-layer graphene cathode for ultrafast and high-capacity aluminum-ion batteries
Source abstract
Abstract
Abstract Graphite is a key cathode material for aluminum-ion batteries (AIBs), but appears poor structural stability and cyclability due to the slow kinetics of intercalation and usage of conductive additives. So far, reasonable design and construction of high-conductive, flexible, binder-free graphitic film cathodes with fast kinetics of anion intercalation mechanism still remains challenging for high-power and high-energy AIBs. Herein, we report the reasonable design for facile construction of high-conductive and mechanically flexible film cathode of high-quality few-layer graphene (FLG) nanosheets for high capacity and fast AIBs, thanks to the strong synergy of ionic surface adsorption/desorption of graphene and ionic intercalation/deintercalation of graphite. The FLG nanosheets prepared by electrochemical cathodic exfoliation from graphite, exhibit predominantly 3–5 layers, extremely low ID/IG ratio of
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Advancements in Battery Materials · Graphene research and applications · Supercapacitor Materials and Fabrication
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (56)
Show source-provided references
1. An overview and future perspectives of aluminum batteries10.1002/adma.201601357 ↗
2. Aluminium-ion batteries: developments and challenges10.1039/C7TA00228A ↗
3. The rechargeable aluminum battery: opportunities and challenges10.1002/anie.201814031 ↗
4. Reconfiguring graphene for high-performance metal-ion battery anodes10.1016/j.ensm.2018.07.013 ↗
5. Tetra-butyl ammonium fluoride-an advanced activator of aluminum surfaces in organic electrolytes for aluminum-air batteries10.1016/j.ensm.2018.08.025 ↗
6. A transformational, high energy density, secondary aluminum ion battery
7. Open-structured V2O5·nH2O nanoflakes as highly reversible cathode material for monovalent and multivalent intercalation batteries10.1002/aenm.201770077 ↗
8. Binder-free V2O5 cathode for greener rechargeable aluminum battery10.1021/am508001h ↗
9. Confirming reversible Al3+ storage mechanism through intercalation of Al3+ into V2O5 nanowires in a rechargeable aluminum battery10.1016/j.ensm.2016.09.001 ↗
10. A binder-free and free-standing cobalt sulfide@ carbon nanotube cathode material for aluminum-ion batteries10.1002/adma.201703824 ↗
11. High-performance aluminum-ion battery with CuS@C microsphere composite cathode10.1021/acsnano.6b06446 ↗
12. Reversible electrochemical intercalation of aluminum in Mo6S810.1021/acs.chemmater.5b01918 ↗
13. Stable CoSe2/carbon nanodice@reduced graphene oxide composites for high-performance rechargeable aluminum-ion batteries10.1039/C8EE00822A ↗
14. Chloroaluminate-doped conducting polymers as positive electrodes in rechargeable aluminum batteries10.1021/jp500593d ↗
15. A novel dual-graphite aluminum-ion battery10.1016/j.ensm.2017.12.010 ↗
16. Rechargeable batteries based on anion intercalation graphite cathodes10.1016/j.ensm.2018.04.023 ↗
17. An ultrafast rechargeable aluminium-ion battery10.1038/nature14340 ↗
18. 3D graphitic foams derived from chloroaluminate anion intercalation for ultrafast aluminum-ion battery10.1002/adma.201602958 ↗
19. Ultrafast all-climate aluminum-graphene battery with quarter-million cycle life10.1126/sciadv.aao7233 ↗
20. A defect-free principle for advanced graphene cathode of aluminum-ion battery10.1002/adma.201605958 ↗
21. Large-sized few-layer graphene enables an ultrafast and long-life aluminum-ion battery10.1002/aenm.201700034 ↗
22. Low-temperature synthesis of edge-rich graphene paper for high-performance aluminum batteries10.1016/j.ensm.2018.06.021 ↗
23. A novel aluminum-ion battery: Al/AlCl3-[EMIm]Cl/Ni3S2@graphene10.1002/aenm.201600137 ↗
24. Two-dimensional vanadium carbide (MXene) as a high-capacity cathode material for rechargeable aluminum batteries10.1021/acsnano.7b05350 ↗
25. Graphene: a cathode material of choice for aluminum-ion batteries10.1002/anie.201802595 ↗
26. Flexible few-layered graphene for the ultrafast rechargeable aluminum-ion battery10.1021/acs.jpcc.6b03657 ↗
27. Three-dimensional flexible and conductive interconnected graphene networks grown by chemical vapour deposition10.1038/nmat3001 ↗
28. Exfoliation of graphite into graphene in aqueous solutions of inorganic salts10.1021/ja5017156 ↗
29. Electrochemically scalable production of fluorine-modified graphene for flexible and high-energy ionogel-based microsupercapacitors10.1021/jacs.8b03235 ↗
30. Graphene anchored with Co3O4 nanoparticles as anode of lithium ion batteries with enhanced reversible capacity and cyclic performance10.1021/nn100740x ↗
31. From molecules to solids with the DMol3 approach10.1063/1.1316015 ↗
32. Implementation of gradient-corrected exchange-correlation potentials in Car-Parrinello total-energy calculations10.1103/PhysRevB.50.4954 ↗
33. Generalized gradient approximation made simple10.1103/PhysRevLett.77.3865 ↗
34. Semiempirical GGA-type density functional constructed with a long-range dispersion correction10.1002/jcc.20495 ↗
35. Quantum and thermal effects in H2 dissociative adsorption: evaluation of free energy barriers in multidimensional quantum systems10.1103/PhysRevLett.72.1124 ↗
36. Perspectives on carbon nanotubes and graphene Raman spectroscopy10.1021/nl904286r ↗
37. Chemical vapor deposition repair of graphene oxide: a route to highly-conductive graphene monolayers10.1002/adma.200901582 ↗
38. Evolution of electrical, chemical, and structural properties of transparent and conducting chemically derived graphene thin films10.1002/adfm.200900166 ↗
39. Electrochemically exfoliated graphene as solution-processable, highly conductive electrodes for organic electronics10.1021/nn400576v ↗
40. Graphene nanoribbons on highly porous 3D graphene for high-capacity and ultrastable Al-ion batteries10.1002/adma.201604118 ↗
41. Graphene aerogel derived compact films for ultrafast and high-capacity aluminum ion batteries10.1016/j.ensm.2019.03.001 ↗
42. Zeolite-templated carbon as an ordered microporous electrode for aluminum batteries10.1021/acsnano.6b07995 ↗
43. Advanced rechargeable aluminium ion battery with a high-quality natural graphite cathode10.1038/ncomms14283 ↗
44. Negative local resistance caused by viscous electron backflow in graphene10.1126/science.aad0201 ↗
45. The interaction of Li+ with single-layer and few-layer graphene10.1021/nl101223k ↗
46. Li+ ion insertion in TiO2 (Anatase). 2. Voltammetry on nanoporous films10.1021/jp970490q ↗
47. Templated nanocrystal-based porous TiO2 flms for next-generation electrochemical capacitors10.1021/ja8057309 ↗
48. MoSe2-covered N,P-doped carbon nanosheets as a long-life and high-rate anode material for sodium-ion batteries10.1002/adfm.201700522 ↗
49. Where do batteries end and supercapacitors begin10.1126/science.1249625 ↗
50. Surface capacitive contributions: towards high rate anode materials for sodium ion batteries10.1016/j.nanoen.2014.12.032 ↗
51. General synthesis of complex nanotubes by gradient electrospinning and controlled pyrolysis10.1038/ncomms8402 ↗
52. Liquid-mediated dense integration of graphene materials for compact capacitive energy storage10.1126/science.1239089 ↗
53. Layer controllable graphene using graphite intercalation compounds with different stage numbers through Li conversion reaction10.1002/admi.201500496 ↗
54. Graphite intercalation compounds (GICs): a new type of promising anode material for lithium-ion batteries10.1002/aenm.201300600 ↗
55. Oxide film efficiently suppresses dendrite growth in aluminum-ion battery10.1021/acsami.7b07024 ↗
56. Dense graphene papers: toward stable and recoverable Al-ion battery cathodes with high volumetric and areal energy and power density10.1016/j.ensm.2018.01.001 ↗