Fluid Unidirectional Transport Induced by Structure and Ambient Elements across Porous Materials: From Principles to Applications

Abstract Spontaneous or nonspontaneous unidirectional fluid transport across multidimension can occur under specific structural designs and ambient elements for porous materials. While existing reviews have extensively summarized unidirectional fluid transport on surfaces, there is an absence of literature summarizing fluid's unidirectional transport across porous materials. This review introduces wetting phenomena observed on natural biological surfaces or porous structures. Subsequently, it offers an overview of diverse principles and potential applications in this field, emphasizing various physical and chemical structural designs (surface energy, capillary size, topographic curvature) and ambient elements (underwater, under oil, pressure, and solar energy). Applications encompass moisture‐wicking fabric, sensors, skincare, fog collection, oil–water separation, electrochemistry, liquid‐based gating, and solar evaporators. Additionally, significant principles and formulas from various studies are compelled to offer readers valuable references. Simultaneously, potential advantages and challenges are critically assessed in these applications and the perspectives are presented.