DataVXAdvanced MaterialsPaper
journal article·2017-11

Selective CO2 Capture and High Proton Conductivity of a Functional Star‐of‐David Catenane Metal–Organic Framework

You‐Gui Huang, Shu‐Qi Wu, Wei‐Hua Deng, Gang Xu, Fa‐Lu Hu, Jonathan P. Hill, Wei Wei, Sheng‐Qun Su, Lok Kumar Shrestha, Osamu Sato, Ming‐Yan Wu, Mao‐Chun Hong, Katsuhiko Ariga

Advanced Materials· Volume 29· Issue 42
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Source abstract

Abstract

Abstract Network structures based on Star‐of‐David catenanes with multiple superior functionalities have been so far elusive, although numerous topologically interesting networks are synthesized. Here, a metal–organic framework featuring fused Star‐of‐David catenanes is reported. Two triangular metallacycles with opposite handedness are triply intertwined forming a Star‐of‐David catenane. Each catenane fuses with its six neighbors to generate a porous twofold intercatenated gyroid framework. The compound possesses exceptional stability and exhibits multiple functionalities including highly selective CO2 capture, high proton conductivity, and coexistence of slow magnetic relaxation and long‐range ordering.
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Research context

OpenAlex topics: Metal-Organic Frameworks: Synthesis and Applications · Covalent Organic Framework Applications · Organic and Molecular Conductors Research

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Xiamen Institute of Rare Earth Materials, Haixi Institute Chinese Academy of Science Xiamen 361021 China

World Premier International (WPI) Center for Materials Nanoarchitectonics (MANA) Institute for Materials Science (NIMS) 1‐1 Namiki Tsukuba Ibaraki 305‐0044 Japan

Institute for Materials Chemistry and Engineering Kyushu University 744 Motooka Nishi‐ku Fukuoka 819‐0395 Japan

Fujian Institute of Research on the Structure of Matter Chinese Academy of Science Fuzhou Fujian 350002 China

Department of Chemistry Capital Normal University Beijing 100048 China

Graduate School of Frontier Science The University of Tokyo Kashiwa 277‐0827 Japan

Funding

JSPS KAKENHI · CREST, JST MEXT, KAKENHI

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