journal article·2023-09Open access

4D Additive–Subtractive Manufacturing of Shape Memory Ceramics

Guo Liu, Xiaofeng Zhang, Xinya Lu, Yan Zhao, Zhifeng Zhou, Jingjun Xu, Jianan Yin, Tao Tang, Peiyu Wang, Shenghui Yi, Jiafeng Fan, Xueshi Zhuo, Yu Hin Chan, Wui Leung Wong, Haidong Bian, Jun Zuo, Yu Dai, Jian Wu, Jian Lu

Advanced Materials· Volume 35· Issue 39

Abstract

Abstract The development of high‐temperature structural materials, such as ceramics, is limited by their extremely high melting points and the difficulty in building complicated architectures. Four‐dimensional (4D) printing helps enhance the geometrical flexibility of ceramics. However, ceramic 4D printing systems are limited by the separate processes for shape and material transformations, low accuracy of morphing systems, low resolution of ceramic structures, and their time‐intensive nature. Here, a paradigm for a one‐step shape/material transformation, high‐2D/3D/4D‐precision, high‐efficiency, and scalable 4D additive–subtractive manufacturing of shape memory ceramics is developed. Original/reverse and global/local multimode shape memory capabilities are achieved using macroscale SiOC‐based ceramic materials. The uniformly deposited Al2O3‐rich layer on the printed SiOC‐based ceramic lattice structures results in an unusually high flame ablation performance of the complex‐shaped ceramics. The proposed framework is expected to broaden the applications of high‐temperature structural materials in the aerospace, electronics, biomedical, and art fields.
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Research context

OpenAlex topics: Additive Manufacturing and 3D Printing Technologies · Advanced Materials and Mechanics · Innovations in Concrete and Construction Materials

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Centre for Advanced Structural Materials City University of Hong Kong Shenzhen Research Institute Greater Bay Joint Division Shenyang National Laboratory for Materials Science Shenzhen 518057 China

CityU‐Shenzhen Futian Research Institute Shenzhen 518045 China

Hong Kong Branch of National Precious Metals Material Engineering Research Center City University of Hong Kong Hong Kong 999077 China

Department of Mechanical Engineering City University of Hong Kong Hong Kong 999077 China

National Engineering Laboratory for Modern Materials Surface Engineering Technology & The Key Lab of Guangdong for Modern Surface Engineering Technology Institute of New Materials Guangdong Academy of Science Guangzhou 510650 China

Department of Materials Science and Engineering City University of Hong Kong Hong Kong 999077 China

State Key Laboratory of Advanced Design and Manufacturing for Vehicle Body College of Mechanical and Vehicle Engineering Hunan University Changsha 410082 China

Shenyang National Laboratory for Materials Science Institute of Metal Research Chinese Academy of Sciences Shenyang 110016 China

School of Physics and Materials Nanchang University Nanchang 330031 China

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