Highly Selective and Sensitive Detection of Volatile Sulfur Compounds by Ionically Conductive Metal‐Organic Frameworks

Abstract High selectivity to specific analyte is essential for chemical sensors but difficult to achieve. For most chemical sensors, although the response to the target analyte can be more significant than interference analytes, they still show obvious responses to the interference analytes. Here, highly selective chemical sensors are developed with negligible responses to other interference vapors. Instead of the widely investigated electronically conductive metal–organic frameworks (EC‐MOFs), ionically conductive MOFs (IC‐MOFs) are used as the sensing materials, and the unique interaction between the ion charge carrier and the analyte is utilized to achieve high sensing selectivity. Through the modulation of the metal nodes (Cu, Co, Ni, Zn, Mg) and organic ligands (H₂TCPP, H₂THPP, H₄BTEC), sensor arrays based on a set of IC‐MOFs are fabricated and achieve highly selective detection toward volatile sulfur compounds (VSCs). H₂S and CH₃SH can be selectively detected at concentrations down to 1 ppb and 1 ppm, respectively. The facile preparation and low cost endow the device with disposability. These results suggest new approaches for the development of highly selective chemical sensors.