journal article·2012-06-26

Compensating Poly(3‐hexylthiophene) Reveals Its Doping Density and Its Strong Exciton Quenching by Free Carriers

Ziqi Liang, Brian A. Gregg

Advanced Materials· Volume 24· Issue 24
Publisher page

Abstract

Adding increasing quantities of an n-type compensating dopant, cobaltocene, to poly(3-hexylthiophene) reveals an almost perfect mirror symmetry between the conductivity and the luminescence intensity. The sharp minimum/maximum shows that the uncompensated p-type doping density is 1.2 × 10(18) cm(-3) and that excitons are strongly quenched by free charge carriers, not by bound charges.
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Research context

OpenAlex topics: Organic Electronics and Photovoltaics · Conducting polymers and applications · Advanced Memory and Neural Computing

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