Low‐Cost Hyperelastic Fuller‐Dome‐Structured Nanocellulose Aerogels by Dual Templates for Personal Thermal Management

Abstract It is critically important to maintain the body's thermal comfort for human beings in extremely cold environments. Cellulose nanofibers (CNF)‐based aerogels represent a promising sustainable material for body's heat retention because of their renewability and low thermal conductivity. However, CNF‐based aerogels often suffer high production costs due to expensive CNF, poor elasticity and/or unsatisfactory thermal insulation owing to improper microstructure design. Here, a facile dual‐template strategy is reported to prepare a low‐cost, hyperelastic, superhydrophobic Fuller‐dome‐structured CNF aerogel (CNF@PU) with low thermal conductivity. The combination of air template by foaming process and ice template enables the formation of a dome‐like microstructure of CNF@PU aerogel, in which CNF serves as rope bars while inexpensive polyurethane (PU) acts as joints. The aerogel combines ultra‐elasticity, low thermal conductivity (24 mW m ⁻¹ K ⁻¹ ), and low costs. The as‐prepared CNF@PU aerogel demonstrates much better heat retention than commercial thermal retention fillers (e.g., Flannelette and goose down), promising its great commercial potential for massively producing warming garments. This work provides a facile approach for creating high‐performance aerogels with tailored microstructure for effective personal thermal management.