Organometallic Hexahapto Functionalization of Single Layer Graphene as a Route to High Mobility Graphene Devices
Source abstract
Abstract
Organometallic hexahapto (η6)-chromium metal complexation of single-layer graphene, which involves constructive rehybridization of the graphene π-system with the vacant chromium dπ orbital, leads to field effect devices which retain a high degree of the mobility with enhanced on-off ratio. This η6 mode of bonding is quite distinct from the modification in electronic structure induced by conventional covalent σ-bond formation with creation of sp3 carbon centers in graphene lattice and this chemistry is reversible.
Source: openalex_inverted_index · Quality: baseline
Research context
OpenAlex topics: Graphene research and applications · Molecular Junctions and Nanostructures · Carbon Nanotubes in Composites
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (42)
Show source-provided references
1. 10.1038/nnano.2008.5810.1038/nnano.2008.58 ↗
2. 10.1021/nl802940s10.1021/nl802940s ↗
3. 10.1126/science.116713010.1126/science.1167130 ↗
4. 10.1021/cm901039j10.1021/cm901039j ↗
5. 10.1103/PhysRevB.82.07340310.1103/PhysRevB.82.073403 ↗
6. 10.1021/ja805732710.1021/ja8057327 ↗
7. 10.1002/pssr.20090311010.1002/pssr.200903110 ↗
8. 10.1039/b920539j10.1039/b920539j ↗
9. 10.1021/nl902741x10.1021/nl902741x ↗
10. 10.1021/nn901899j10.1021/nn901899j ↗
11. 10.1021/ja200118b10.1021/ja200118b ↗
12. 10.1039/c0sc00634c10.1039/c0sc00634c ↗
13. 10.1021/nl102112810.1021/nl1021128 ↗
14. 10.1021/nl902362q10.1021/nl902362q ↗
15. 10.1021/ar200302g10.1021/ar200302g ↗
16. 10.1002/anie.20120132010.1002/anie.201201320 ↗
17. 10.1002/ange.20120132010.1002/ange.201201320 ↗
18. 10.1021/jp304374r10.1021/jp304374r ↗
19. 10.1021/jz200426d10.1021/jz200426d ↗
20. 10.1088/0022-3727/45/15/15400910.1088/0022-3727/45/15/154009 ↗
21. 10.1002/smll.20100224410.1002/smll.201002244 ↗
22. 10.1021/nl200803q10.1021/nl200803q ↗
23. 10.1016/S1369-7021(12)70118-910.1016/S1369-7021(12)70118-9 ↗
24. 10.1103/PhysRevLett.105.05680210.1103/PhysRevLett.105.056802 ↗
25. 10.1063/1.472371710.1063/1.4723717 ↗
26. 10.1002/macp.20110066110.1002/macp.201100661 ↗
27. 10.1002/poc.195910.1002/poc.1959 ↗
28. 10.1016/j.matlet.2012.04.08610.1016/j.matlet.2012.04.086 ↗
29. 10.1063/1.278967310.1063/1.2789673 ↗
30. 10.1016/0022-328X(85)88005-010.1016/0022-328X(85)88005-0 ↗
31. 10.1021/jo00075a00810.1021/jo00075a008 ↗
32. 10.1007/b9448910.1007/b94489 ↗
33. 10.1080/0094571740806962910.1080/00945717408069629 ↗
34. 10.1016/S0022-328X(00)96208-910.1016/S0022-328X(00)96208-9 ↗
35. 10.1021/jo00050a02310.1021/jo00050a023 ↗
36. 10.1021/nl101437p10.1021/nl101437p ↗
37. 10.1002/smll.20100155510.1002/smll.201001555 ↗
38. 10.1021/nn203719a10.1021/nn203719a ↗
39. 10.1021/om800505j10.1021/om800505j ↗
40. 10.1016/j.ccr.2010.05.00410.1016/j.ccr.2010.05.004 ↗
41. 10.1021/jp109782q10.1021/jp109782q ↗
42. 10.1021/om000269r10.1021/om000269r ↗