DataVXAdvanced MaterialsPaper
journal article·2021-12

Multifunctional Macroassembled Graphene Nanofilms with High Crystallinity

Li Peng, Ying Han, Meihui Wang, Xiaoxue Cao, Junfeng Gao, Yingjun Liu, Xianjue Chen, Bin Wang, Bo Wang, Chongyang Zhu, Xiao Wang, Ke Cao, Ming Huang, Benjamin V. Cunning, Jintao Pang, Wendao Xu, Yibin Ying, Zhen Xu, Wenzhang Fang, Yang Lu, Rodney S. Ruoff, Chao Gao

Advanced Materials· Volume 33· Issue 49
Publisher page
Source abstract

Abstract

Abstract A “cooling–contraction” method to separate large‐area (up to 4.2 cm in lateral size) graphene oxide (GO)‐assembled films (of nanoscale thickness) from substrates is reported. Heat treatment at 3000 °C of such free‐standing macroscale films yields highly crystalline “macroassembled graphene nanofilms” (nMAGs) with 16–48 nm thickness. These nMAGs present tensile strength of 5.5–11.3 GPa (with ≈3 µm gauge length), electrical conductivity of 1.8–2.1 MS m−1, thermal conductivity of 2027–2820 W m−1 K−1, and carrier relaxation time up to ≈23 ps. As a demonstration application, an nMAG‐based sound‐generator shows a 30 µs response and sound pressure level of 89 dB at 1 W cm−2. A THz metasurface fabricated from nMAG has a light response of 8.2% for 0.159 W mm−2 and can detect down to 0.01 ppm of glucose. The approach provides a straightforward way to form highly crystallized graphene nanofilms from low‐cost GO sheets.
Source: crossref · Quality: baseline

Research context

NanomaterialsMaterials processing

OpenAlex topics: Graphene research and applications · Advanced Thermoelectric Materials and Devices · 2D Materials and Applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

MOE Key Laboratory of Macromolecular Synthesis and Functionalization Department of Polymer Science and Engineering Zhejiang University 38 Zheda Road Hangzhou 310027 P. R. China

Center for Multidimensional Carbon Materials (CMCM) Institute for Basic Science (IBS) Ulsan 44919 Republic of Korea

Department of Mechanical Engineering City University of Hong Kong Kowloon Hong Kong SAR P. R. China

Department of Chemistry Ulsan National Institute of Science and Technology (UNIST) Ulsan 44919 Republic of Korea

Key Laboratory of Materials Modification by Laser Ion and Electron Beams Ministry of Education Dalian University of Technology Dalian 116024 P. R. China

Shenzhen Key Laboratory of Nanobiomechanics Shenzhen Institutes of Advanced Technology Chinese Academy of Science Shenzhen Guangdong 518055 P. R. China

The State Key Laboratory of Fluid Power and Mechatronic Systems Zhejiang University Hangzhou 310027 P. R. China

College of Biosystems Engineering and Food Science Zhejiang University 866 Yuhangtang Road Hangzhou Zhejiang 310058 P. R. China

Department of Materials Science and Engineering Ulsan National Institute of Science and Technology (UNIST) Ulsan 44919 Republic of Korea

School of Energy and Chemical Engineering Ulsan National Institute of Science and Technology (UNIST) Ulsan 44919 Republic of Korea

Funding

Institute for Basic Science · Fundamental Research Funds for the Central Universities · National Natural Science Foundation of China · China Postdoctoral Science Foundation · City University of Hong Kong

References (43)

Show source-provided references
1. 10.1002/adma.20120457610.1002/adma.201204576 ↗
2. 10.1038/ncomms158310.1038/ncomms1583 ↗
3. 10.1002/ange.20100469210.1002/ange.201004692 ↗
4. 10.1002/adma.20130350310.1002/adma.201303503 ↗
5. 10.1002/adma.20170058910.1002/adma.201700589 ↗
6. 10.1038/nnano.2015.32210.1038/nnano.2015.322 ↗
7. 10.1038/nmat306410.1038/nmat3064 ↗
8. 10.1038/ncomms478210.1038/ncomms4782 ↗
9. 10.1002/adma.20190303910.1002/adma.201903039 ↗
10. Sharma B. L. · 2013 · 113
11. 10.1007/s10118-021-2515-110.1007/s10118-021-2515-1 ↗
12. 10.1002/adma.20140405410.1002/adma.201404054 ↗
13. 10.1002/adma.20140406910.1002/adma.201404069 ↗
14. 10.1021/acsnano.5b0126110.1021/acsnano.5b01261 ↗
15. 10.1021/acs.chemmater.6b0387510.1021/acs.chemmater.6b03875 ↗
16. Lee C. · 2015
17. 10.1021/nn101550610.1021/nn1015506 ↗
18. 10.1016/j.ceramint.2019.04.16510.1016/j.ceramint.2019.04.165 ↗
19. 10.1103/PhysRevLett.106.10550510.1103/PhysRevLett.106.105505 ↗
20. 10.1016/j.carbon.2007.11.01510.1016/j.carbon.2007.11.015 ↗
21. 10.1126/sciadv.150138210.1126/sciadv.1501382 ↗
22. 10.1038/s41467-019-14130-010.1038/s41467-019-14130-0 ↗
23. 10.1126/science.115799610.1126/science.1157996 ↗
24. 10.1002/adfm.20200538110.1002/adfm.202005381 ↗
25. 10.1038/ncomms418610.1038/ncomms4186 ↗
26. 10.1126/science.aaa650210.1126/science.aaa6502 ↗
27. 10.1063/1.369087110.1063/1.3690871 ↗
28. 10.1016/j.carbon.2018.12.05710.1016/j.carbon.2018.12.057 ↗
29. 10.1038/ncomms1217410.1038/ncomms12174 ↗
30. 10.1038/ncomms910510.1038/ncomms9105 ↗
31. 10.1016/j.carbon.2019.09.06610.1016/j.carbon.2019.09.066 ↗
32. 10.1021/ja078267m10.1021/ja078267m ↗
33. 10.1002/adma.20160244410.1002/adma.201602444 ↗
34. 10.1021/nl902362q10.1021/nl902362q ↗
35. 10.1063/1.482112110.1063/1.4821121 ↗
36. 10.1039/c2nr30417a10.1039/c2nr30417a ↗
37. 10.1002/adma.20120178210.1002/adma.201201782 ↗
38. Tian H. · 2014 · 556
39. 10.1038/ncomms1457910.1038/ncomms14579 ↗
40. 10.1016/j.snb.2020.12784110.1016/j.snb.2020.127841 ↗
41. 10.1016/j.carbon.2018.09.05010.1016/j.carbon.2018.09.050 ↗
42. 10.1016/j.mattod.2019.08.00210.1016/j.mattod.2019.08.002 ↗
43. 10.1016/j.foodchem.2016.09.03210.1016/j.foodchem.2016.09.032 ↗