Electrochemical Hydrogen Production Coupling with the Upgrading of Organic and Inorganic Chemicals

Abstract Electrocatalytic water splitting powered by renewable energy is a green and sustainable method for producing high‐purity H₂. However, in conventional water electrolysis, the anodic oxygen evolution reaction (OER) involves a four‐electron transfer process with inherently sluggish kinetics, which severely limits the overall efficiency of water splitting. Recently, replacing OER with thermodynamically favorable oxidation reactions, coupled with the hydrogen evolution reaction, has garnered significant attention and achieved remarkable progress. This strategy not only offers a promising route for energy‐saving H₂ production but also enables the simultaneous synthesis of high‐value‐added products or the removal of pollutants at the anode. Researchers successfully demonstrate the upgrading of numerous organic and inorganic alternatives through this approach. In this review, the latest advances in the coupling of electrocatalytic H₂ production and the upgrading of organic and inorganic alternative chemicals are summarized. What's more, the optimization strategy of catalysts, structure–performance relationship, and catalytic mechanism of various reactions are well discussed in each part. Finally, the current challenges and future prospects in this field are outlined, aiming to inspire further innovative breakthroughs in this exciting area of research.