2D Amorphous Iron Selenide Sulfide Nanosheets for Stable and Rapid Sodium‐Ion Storage

Abstract Sodium ion batteries (SIBs) suffer from large electrode volume change and sluggish redox kinetics for the relatively large ionic radius of sodium ions, raising a significant challenge to improve their long‐term cyclability and rate capacity. Here, it is proposed to apply 2D amorphous iron selenide sulfide nanosheets (a‐FeSeS NSs) as an anode material for SIBs and demonstrate that they exhibit remarkable rate capability of 528.7 mAh g⁻¹ at 1 A g⁻¹ and long‐life cycle (10 000 cycles) performance (300.4 mAh g⁻¹). This performance is much more superior to that of the previously reported Fe‐based anode materials, which is attributed to their amorphous structure that alleviates volume expansion of electrode, 2D nature that facilitates electrons/ions transfer, and the S/Se double anions that offer more reaction sites and stabilize the amorphous structure. Such a 2D amorphous strategy provides a fertile platform for structural engineering of other electrode materials, making a more secure energy prospect closer to a reality.