journal article·2021-03Open access

General Programmable Growth of Hybrid Core–Shell Nanostructures with Liquid Metal Nanodroplets

Long Ren, Ningyan Cheng, Xingkun Man, Dongchen Qi, Yundan Liu, Guobao Xu, Dandan Cui, Nana Liu, Jianxin Zhong, Germanas Peleckis, Xun Xu, Shi Xue Dou, Yi Du

Advanced Materials· Volume 33· Issue 11

Abstract

Abstract Core–shell and hollow nanostructures have been receiving significant interest due to their potential in wide scientific and technological fields. Given such large scope, however, they still lag far behind in terms of the ambition toward controllably, or even programmatically, synthesizing libraries of core–shell structures on a large scale. Here, a general route for the programmable preparation of complex core–shell nanostructures by using liquid metal (LM) droplets as reformable templates is presented, and the triggering of a localized galvanic replacement reaction in one ultrasonication system is demonstrated. Benefiting from the activity and mobility of the metal components in LM templates, high‐level compositional diversity control and quantitative regulation of both the core and the shell layers of the heterogeneous products are achieved, which cannot be realized with a solid‐template synthetic route.
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Research context

OpenAlex topics: Copper-based nanomaterials and applications · Pickering emulsions and particle stabilization · Nanomaterials and Printing Technologies

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Institute for Superconducting and Electronic Materials (ISEM) Australian Institute for Innovative Materials (AIIM) University of Wollongong Wollongong NSW 2500 Australia

BUAA‐UOW Joint Research Centre, and School of Physics Beihang University Beijing 100091 China

International School of Materials Science and Engineering Wuhan University of Technology Hubei 430070 China

Centre for Materials Science School of Chemistry and Physics Queensland University of Technology Brisbane Queensland 4001 Australia

School of Physics and Optoelectronic Xiangtan University Hunan 411105 China

School of Materials Science and Engineering Xiangtan University Hunan 411105 China

Funding

Australian Research Council · National Natural Science Foundation of China · Natural Science Foundation of Beijing Municipality · Natural Science Foundation of Hunan Province

References (32)

Show source-provided references
1. 10.1021/acs.chemrev.5b0073110.1021/acs.chemrev.5b00731 ↗
2. 10.1021/acs.chemrev.6b0037410.1021/acs.chemrev.6b00374 ↗
3. 10.1002/adma.20160456310.1002/adma.201604563 ↗
4. 10.1021/acs.chemrev.9b0023410.1021/acs.chemrev.9b00234 ↗
5. 10.1016/j.nantod.2019.10083410.1016/j.nantod.2019.100834 ↗
6. 10.1126/science.118476910.1126/science.1184769 ↗
7. 10.1038/ncomms1025410.1038/ncomms10254 ↗
8. 10.1126/science.aah613310.1126/science.aah6133 ↗
9. 10.1126/science.109656610.1126/science.1096566 ↗
10. 10.1126/science.121282210.1126/science.1212822 ↗
11. 10.1002/adma.20130282010.1002/adma.201302820 ↗
12. 10.1126/science.123475110.1126/science.1234751 ↗
13. 10.1039/C4NR02025A10.1039/C4NR02025A ↗
14. 10.1002/adma.20160291410.1002/adma.201602914 ↗
15. 10.1016/j.mattod.2019.10.00710.1016/j.mattod.2019.10.007 ↗
16. 10.1126/science.aao424910.1126/science.aao4249 ↗
17. 10.1039/C7CS00043J10.1039/C7CS00043J ↗
18. 10.1021/acsnano.9b0484310.1021/acsnano.9b04843 ↗
19. 10.1021/jacs.6b0595710.1021/jacs.6b05957 ↗
20. 10.1021/acs.langmuir.8b0230310.1021/acs.langmuir.8b02303 ↗
21. 10.1002/adfm.20190164910.1002/adfm.201901649 ↗
22. 10.1039/C9NR02458A10.1039/C9NR02458A ↗
23. 10.1021/acsomega.9b0084010.1021/acsomega.9b00840 ↗
24. 10.1039/D0NA00148A10.1039/D0NA00148A ↗
25. 10.1016/j.matt.2020.03.01610.1016/j.matt.2020.03.016 ↗
26. 10.3891/acta.chem.scand.04-106610.3891/acta.chem.scand.04-1066 ↗
27. Müller U. · 1993
28. 10.1038/nphys239610.1038/nphys2396 ↗
29. 10.1038/nmat470510.1038/nmat4705 ↗
30. 10.1039/c0cs00176g10.1039/c0cs00176g ↗
31. 10.1021/jp802804u10.1021/jp802804u ↗
32. 10.1002/advs.20180027110.1002/advs.201800271 ↗