Advancing high-voltage halide-based solid-state batteries: Interfacial challenges, material innovations, and applications
Source abstract
Abstract
All-solid-state batteries represent a promising avenue for next-generation energy storage systems, offering the potential for high energy density and enhanced safety. Among solid-state electrolytes, halide solid-state electrolytes stand out due to their superior ionic conductivities , oxidation stability, and mechanical moldability. However, several challenges remain, particularly at the interface between halide solid-state electrolytes and ultra-high voltage cathodes, resulting in suboptimal electrochemical performance . This review systematically examines the interfacial issues that hinder the performance of halide-based all-solid-state batteries, focusing on interfacial reactions, mechanical failure, and suboptimal ion/electron transport. Furthermore, we explore three strategies to address these challenges: electrolyte design and refinement, cathode surface modification, and composite cathode preparation. We also discuss the practical challenges of transitioning from laboratory research to industrial-scale applications, offering a roadmap for future advancements in high-performance halide-based all-solid-state batteries.
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Research context
OpenAlex topics: Advancements in Battery Materials · Advanced Battery Materials and Technologies · Advanced battery technologies research
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
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