DataVXAdvanced MaterialsPaper
journal article·2023-03Open access

Versatile Assembly of Metal–Phenolic Network Foams Enabled by Tannin–Cellulose Nanofibers

Bruno D. Mattos, Ya Zhu, Blaise L. Tardy, Marco Beaumont, Ana Carolina R. Ribeiro, André L. Missio, Caio G. Otoni, Orlando J. Rojas

Advanced Materials· Volume 35· Issue 12
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Source abstract

Abstract

Abstract Metal–phenolic network (MPN) foams are prepared using colloidal suspensions of tannin‐containing cellulose nanofibers (CNFs) that are ice‐templated and thawed in ethanolic media in the presence of metal nitrates. The MPN facilitates the formation of solid foams by air drying, given the strength and self‐supporting nature of the obtained tannin–cellulose nanohybrid structures. The porous characteristics and (dry and wet) compression strength of the foams are rationalized by the development of secondary, cohesive metal‐phenolic layers combined with a hydrogen bonding network involving the CNF. The shrinkage of the MPN foams is as low as 6% for samples prepared with 2.5–10% tannic acid (or condensed tannin at 2.5%) with respect to CNF content. The strength of the MPN foams reaches a maximum at 10% tannic acid (using Fe(III) ions), equivalent to a compressive strength 70% higher than that produced with tannin‐free CNF foams. Overall, a straightforward framework is introduced to synthesize MPN foams whose physical and mechanical properties are tailored by the presence of tannins as well as the metal ion species that enable the metal–phenolic networking. Depending on the metal ion, the foams are amenable to modification according to the desired application.
Source: crossref · Quality: baseline

Research context

Nanomaterials

OpenAlex topics: Lignin and Wood Chemistry · Advanced Cellulose Research Studies · Polymer composites and self-healing

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Department of Bioproducts and Biosystems School of Chemical Engineering Aalto University Vuorimiehentie 1 FI‐00076 Espoo Finland

Technological Development Center Materials Science and Engineering (PPGCEM) Federal University of Pelotas (UFPel) Gomes Carneiro 1 Pelotas RS 96010‐610 Brazil

Department of Chemical Engineering Research and Innovation Center on CO2 and Hydrogen Center for Membrane and Advanced Water Technology Khalifa University of Science and Technology P.O. Box 127788 Abu Dhabi United Arab Emirates

Department of Chemistry Institute of Chemistry of Renewable Resources University of Natural Resources and Life Sciences Konrad‐Lorenz‐Str. 24 3430 Tulln Austria

Department of Materials Engineering (DEMa) Federal University of São Carlos (UFSCar) Rod. Washington Luís km 235 São Carlos SP 13565‐905 Brazil

Bioproducts Institute Department of Chemical and Biological Engineering Department of Chemistry and Department of Wood Science University of British Columbia Vancouver British Columbia V6T 1Z4 Canada

Funding

European Research Council · Canada Foundation for Innovation

References (57)

Show source-provided references
1. 10.1021/acs.chemrev.0c0133310.1021/acs.chemrev.0c01333 ↗
2. 10.1021/acsnano.8b0108410.1021/acsnano.8b01084 ↗
3. 10.1073/pnas.150287011210.1073/pnas.1502870112 ↗
4. 10.1039/C7TA02807E10.1039/C7TA02807E ↗
5. 10.1021/acsnano.1c0708410.1021/acsnano.1c07084 ↗
6. 10.1038/nnano.2014.24810.1038/nnano.2014.248 ↗
7. 10.1021/acssensors.1c0047310.1021/acssensors.1c00473 ↗
8. 10.1021/acsnano.2c0488310.1021/acsnano.2c04883 ↗
9. 10.1038/s41467-021-22682-310.1038/s41467-021-22682-3 ↗
10. 10.1021/acsnano.0c0221110.1021/acsnano.0c02211 ↗
11. 10.1016/j.carbpol.2021.11874110.1016/j.carbpol.2021.118741 ↗
12. 10.1021/acsanm.9b0244110.1021/acsanm.9b02441 ↗
13. 10.1038/nnano.2010.15510.1038/nnano.2010.155 ↗
14. 10.1002/adma.20220250410.1002/adma.202202504 ↗
15. 10.1021/acs.biomac.0c0159610.1021/acs.biomac.0c01596 ↗
16. 10.1038/s41570-018-0010-110.1038/s41570-018-0010-1 ↗
17. 10.1021/jacs.1c0503210.1021/jacs.1c05032 ↗
18. 10.1002/adma.20160135110.1002/adma.201601351 ↗
19. 10.1021/acsabm.2c0013610.1021/acsabm.2c00136 ↗
20. 10.1002/anie.20131113610.1002/anie.201311136 ↗
21. 10.1039/C8GC00064F10.1039/C8GC00064F ↗
22. 10.1021/acs.chemrev.1c0104210.1021/acs.chemrev.1c01042 ↗
23. 10.1002/anie.20160841310.1002/anie.201608413 ↗
24. 10.1039/C9NR04142G10.1039/C9NR04142G ↗
25. 10.1021/acsnano.9b0552110.1021/acsnano.9b05521 ↗
26. 10.1038/nnano.2016.17210.1038/nnano.2016.172 ↗
27. 10.1002/anie.20191350910.1002/anie.201913509 ↗
28. 10.1021/acssuschemeng.9b0433210.1021/acssuschemeng.9b04332 ↗
29. 10.1021/acsami.9b0983010.1021/acsami.9b09830 ↗
30. 10.1016/j.seppur.2017.06.01010.1016/j.seppur.2017.06.010 ↗
31. 10.1016/j.jclepro.2018.02.20510.1016/j.jclepro.2018.02.205 ↗
32. 10.1021/acs.biomac.9b0173310.1021/acs.biomac.9b01733 ↗
33. 10.1021/acs.biomac.2c0031310.1021/acs.biomac.2c00313 ↗
34. 10.1021/acssuschemeng.0c0560110.1021/acssuschemeng.0c05601 ↗
35. 10.3390/nano908114210.3390/nano9081142 ↗
36. 10.1021/acs.jpcb.1c0141610.1021/acs.jpcb.1c01416 ↗
37. 10.1021/bm700972k10.1021/bm700972k ↗
38. 10.1007/s10570-018-2189-110.1007/s10570-018-2189-1 ↗
39. 10.1038/s41598-020-73899-z10.1038/s41598-020-73899-z ↗
40. 10.1021/acs.biomac.1c0065010.1021/acs.biomac.1c00650 ↗
41. 10.1021/acsnano.8b0723510.1021/acsnano.8b07235 ↗
42. 10.7150/thno.5871110.7150/thno.58711 ↗
43. 10.1039/C5NJ02131F10.1039/C5NJ02131F ↗
44. 10.1039/D1MA00841B10.1039/D1MA00841B ↗
45. 10.1021/acssuschemeng.2c0267810.1021/acssuschemeng.2c02678 ↗
46. 10.1016/j.indcrop.2012.07.03910.1016/j.indcrop.2012.07.039 ↗
47. 10.1016/j.polymer.2021.12362710.1016/j.polymer.2021.123627 ↗
48. 10.1016/j.jaap.2017.06.00310.1016/j.jaap.2017.06.003 ↗
49. 10.1021/acssuschemeng.8b0485110.1021/acssuschemeng.8b04851 ↗
50. 10.1016/j.jcis.2021.04.07110.1016/j.jcis.2021.04.071 ↗
51. 10.1039/D2TB00717G10.1039/D2TB00717G ↗
52. 10.1002/smll.20210031410.1002/smll.202100314 ↗
53. 10.1021/ja00231a01710.1021/ja00231a017 ↗
54. 10.1002/admi.20190033310.1002/admi.201900333 ↗
55. 10.1002/anie.20191060310.1002/anie.201910603 ↗
56. 10.1002/adsu.20210030810.1002/adsu.202100308 ↗
57. 10.1021/acsami.8b1440910.1021/acsami.8b14409 ↗