journal article·2022-01

Ionic Crosslinking‐Induced Nanochannels: Nanophase Separation for Ion Transport Promotion

Weipeng Chen, Tiandu Dong, Yun Xiang, Yongchao Qian, Xiaolu Zhao, Weiwen Xin, Xiang‐Yu Kong, Lei Jiang, Liping Wen

Advanced Materials· Volume 34· Issue 3
Publisher page

Abstract

Abstract Charge‐governed ion transport is crucial to numerous industries, and the advanced membrane is the essential component. In nature, the efficient and selective ion transport is mainly governed by the charged ion channels located in cell membrane, indicating the architecture with functional differentiation. Inspired by this architecture, a membrane by ionic crosslinking sulfonated poly(arylene ether ketone) and imidazolium‐functionalized poly(arylene ether sulfone) is designed and fabricated to make full use of the charges. This ionic crosslinking is designed to realize nanophase separation to aggregate the ion pathways in the membrane, which results in excellent ion selectivity and high ion conductivity. With the excellent ion transport behavior, ionic crosslinking membrane shows great potential in osmotic energy conversion, which maximum power density can be up to 16.72 W m−2. This design of ionic crosslinking‐induced nanophase separation offers a roadmap for ion transport promotion.
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Research context

OpenAlex topics: Nanopore and Nanochannel Transport Studies · Fuel Cells and Related Materials · Membrane-based Ion Separation Techniques

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

CAS Key Laboratory of Bio‐inspired Materials and Interfacial Science Technical Institute of Physics and Chemistry Chinese Academy of Sciences Beijing 100190 P. R. China

School of Future Technology University of Chinese Academy of Sciences Beijing 100049 P. R. China

Shanxi Key Laboratory of Macromolecular Science and Technology School of Chemistry and Chemical Engineering Northwestern Polytechnical University Xi'an 710072 P. R. China

Funding

National Natural Science Foundation of China

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