Rational Design of Benzotrithiophene‐Diketopyrrolopyrrole‐Containing Donor‐Acceptor Polymers for Improved Charge Carrier Transport

Two new donor-acceptor polymers containing benzo[2,1-b:3,4-b':5,6-c'']trithiophene (BTT) as donor and diketopyrrolopyrrole (DPP) as acceptor are synthesized and applied in OFETs. By tuning the alkyl substituents of the polymers, a striking difference in packing order, thin-film arrangement, and charge carrier transport is observed. The polymer without substituents at the BTT exhibits a hole mobility two orders of magnitude higher than that with alkyl chains therein. As a service to our authors and readers, this journal provides supporting information supplied by the authors. Such materials are peer reviewed and may be re-organized for online delivery, but are not copy-edited or typeset. Technical support issues arising from supporting information (other than missing files) should be addressed to the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.