A Perspective on Uniform Plating Behavior of Mg Metal Anode: Diffusion Limited Theory versus Nucleation Theory

Abstract Utilizing metal anode is the most attractive way to meet the urgent demand for rechargeable batteries with high energy density. Unfortunately, the formation of dendrites, which is caused by uneven plating behavior, always threaten the safety of the batteries. To explore the origin of different plating behavior and predict the plating morphology of anode under a variety of operating conditions, multifarious models have been developed. However, abuse of models has led to conflictive views. In this perspective, to clarify the controversial reports on magnesium (Mg) metal plating behavior, the previously proposed models are elaborated that govern the plating process. Through linking various models and clarifying their boundary conditions, a scheme is drawn to illustrate the strategy for achieving the most dense and uniform plating morphology, which also explains the seemingly contradictory of diffusion limited theory and nucleation theory on uniform plating. This perspective will undoubtedly enhance the understanding on the metal anode plating process and provide meaningful guidance for the development of metal anode batteries.