Vanadium Oxide‐Doped Laser‐Induced Graphene Multi‐Parameter Sensor to Decouple Soil Nitrogen Loss and Temperature
Source abstract
Abstract
Abstract Monitoring nitrogen utilization efficiency and soil temperature in agricultural systems for timely intervention is essential for crop health with reduced environmental pollution. Herein, this work presents a high‐performance multi‐parameter sensor based on vanadium oxide (VO X )‐doped laser‐induced graphene (LIG) foam to completely decouple nitrogen oxides (NO X ) and temperature. The highly porous 3D VO X ‐doped LIG foam composite is readily obtained by laser scribing vanadium sulfide (V 5 S 8 )‐doped block copolymer and phenolic resin self‐assembled films. The heterojunction formed at the LIG/VO X interface provides the sensor with enhanced response to NO X and an ultralow limit of detection of 3 ppb (theoretical estimate of 451 ppt) at room temperature. The sensor also exhibits a wide detection range, fast response/recovery, good selectivity, and stability over 16 days. Meanwhile, the sensor can accurately detect temperature over a wide linear range of 10–110 °C. The encapsulation of the sensor with a soft membrane further allows for temperature sensing without being affected by NO X . The unencapsulated sensor operated at elevated temperature removes the influences of relative humidity and temperature variations for accurate NO X measurements. The capability to decouple nitrogen loss and soil temperature paves the way for the development of future multimodal decoupled electronics for precision agriculture and health monitoring.
Source: crossref · Quality: baseline
Research context
OpenAlex topics: Gas Sensing Nanomaterials and Sensors · Analytical Chemistry and Sensors · Advanced Sensor and Energy Harvesting Materials
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
State Key Laboratory of Reliability and Intelligence of Electrical Equipment School of Health Sciences and Biomedical Engineering Hebei University of Technology Tianjin 300130 P. R. China
State Key Laboratory for Reliability and Intelligence of Electrical Equipment Hebei Key Laboratory of Smart Sensing and Human‐Robot Interaction School of Mechanical Engineering Hebei University of Technology Tianjin 300130 P. R. China
Department of Engineering Science and Mechanics The Pennsylvania State University University Park 16802 USA
State Key Laboratory of Reliability and Intelligence of Electrical Equipment Key Laboratory of Bioelectromagnetics and Neuroengineering of Hebei Province School of Electrical Engineering Hebei University of Technology Tianjin 300130 P. R. China
School of Architecture and Art Hebei University of Technology Tianjin 300130 P. R. China
Tianjin Tianzhong Yimai Technology Development Co. Ltd Tianjin 300384 P. R. China
Fujian Key Laboratory of Functional Marine Sensing Materials College of Material and Chemical Engineering Minjiang University Fuzhou 350108 P. R. China
Funding
China Postdoctoral Science Foundation · Pennsylvania State University · National Natural Science Foundation of China · National Institutes of Health · National Science Foundation
References (97)
Show source-provided references
1. 10.3389/fpls.2022.85419510.3389/fpls.2022.854195 ↗
2. 10.1126/science.118612010.1126/science.1186120 ↗
3. 10.1016/j.envpol.2004.10.00710.1016/j.envpol.2004.10.007 ↗
4. 10.1016/j.snb.2022.13157910.1016/j.snb.2022.131579 ↗
5. 10.1088/1748-9326/ac16a310.1088/1748-9326/ac16a3 ↗
6. 10.1016/j.soilbio.2012.11.01210.1016/j.soilbio.2012.11.012 ↗
7. 10.1016/0167-8809(90)90203-P10.1016/0167-8809(90)90203-P ↗
8. 10.1002/2015WR01842510.1002/2015WR018425 ↗
9. 10.1006/jaer.2000.057710.1006/jaer.2000.0577 ↗
10. 10.1002/adma.20200776410.1002/adma.202007764 ↗
11. 10.1002/advs.20220247010.1002/advs.202202470 ↗
12. 10.1021/acsami.1c2200110.1021/acsami.1c22001 ↗
13. 10.1016/j.nanoen.2022.10760610.1016/j.nanoen.2022.107606 ↗
14. 10.1016/j.cej.2022.13663110.1016/j.cej.2022.136631 ↗
15. 10.1021/nn402242210.1021/nn4022422 ↗
16. 10.1039/C5NR03633J10.1039/C5NR03633J ↗
17. 10.1002/adfm.20200336010.1002/adfm.202003360 ↗
18. 10.1016/j.apsusc.2021.15153510.1016/j.apsusc.2021.151535 ↗
19. 10.1007/s13391-018-0044-z10.1007/s13391-018-0044-z ↗
20. 10.1016/j.snb.2022.13302710.1016/j.snb.2022.133027 ↗
21. 10.1016/j.cej.2022.13644910.1016/j.cej.2022.136449 ↗
22. 10.1016/j.snb.2021.12965710.1016/j.snb.2021.129657 ↗
23. 10.1016/j.snb.2021.13065310.1016/j.snb.2021.130653 ↗
24. 10.1007/s00604-021-05157-610.1007/s00604-021-05157-6 ↗
25. 10.1007/s12274-021-3441-910.1007/s12274-021-3441-9 ↗
26. 10.1021/acsnano.1c0580610.1021/acsnano.1c05806 ↗
27. 10.1016/j.nanoen.2022.10780710.1016/j.nanoen.2022.107807 ↗
28. 10.1021/acs.macromol.8b0176610.1021/acs.macromol.8b01766 ↗
29. 10.1126/science.aab049210.1126/science.aab0492 ↗
30. 10.1021/acsami.2c0206110.1021/acsami.2c02061 ↗
31. 10.1016/j.snb.2021.13094710.1016/j.snb.2021.130947 ↗
32. 10.1016/j.cej.2021.13227410.1016/j.cej.2021.132274 ↗
33. 10.1007/s00604-020-4182-210.1007/s00604-020-4182-2 ↗
34. 10.1007/s10854-022-08454-910.1007/s10854-022-08454-9 ↗
35. 10.1016/j.jallcom.2021.16183710.1016/j.jallcom.2021.161837 ↗
36. 10.1021/acsami.6b1488210.1021/acsami.6b14882 ↗
37. 10.1016/j.apsusc.2017.04.09710.1016/j.apsusc.2017.04.097 ↗
38. 10.1016/j.jssc.2005.03.03410.1016/j.jssc.2005.03.034 ↗
39. Przes̈niak‐Welenc M. · J. Nanomater. · 2015 · 351
40. 10.1016/j.tsf.2013.03.13710.1016/j.tsf.2013.03.137 ↗
41. 10.1002/cvde.20060654010.1002/cvde.200606540 ↗
42. 10.1016/j.jpowsour.2007.06.16610.1016/j.jpowsour.2007.06.166 ↗
43. 10.1021/acsnano.1c0305010.1021/acsnano.1c03050 ↗
44. 10.1016/j.nanoso.2021.10082410.1016/j.nanoso.2021.100824 ↗
45. 10.1016/j.ceramint.2021.02.14410.1016/j.ceramint.2021.02.144 ↗
46. 10.1021/acsnano.7b0214810.1021/acsnano.7b02148 ↗
47. 10.1038/s41378-022-00414-x10.1038/s41378-022-00414-x ↗
48. 10.3390/molecules2623726210.3390/molecules26237262 ↗
49. 10.1016/j.mssp.2021.10567010.1016/j.mssp.2021.105670 ↗
50. 10.1021/acsami.1c2045610.1021/acsami.1c20456 ↗
51. 10.1007/s00604-020-4182-210.1007/s00604-020-4182-2 ↗
52. 10.1002/adma.20180362110.1002/adma.201803621 ↗
53. 10.1021/acssensors.8b0054410.1021/acssensors.8b00544 ↗
54. 10.1021/acs.chemmater.6b0508410.1021/acs.chemmater.6b05084 ↗
55. 10.1016/j.jpowsour.2019.22767410.1016/j.jpowsour.2019.227674 ↗
56. 10.1016/0925-4005(92)80206-D10.1016/0925-4005(92)80206-D ↗
57. 10.1016/j.snb.2022.13211310.1016/j.snb.2022.132113 ↗
58. 10.1016/j.snb.2021.12999610.1016/j.snb.2021.129996 ↗
59. 10.1351/pac19956710169910.1351/pac199567101699 ↗
60. 10.1016/j.apsusc.2015.09.16810.1016/j.apsusc.2015.09.168 ↗
61. 10.1109/JSEN.2021.310238210.1109/JSEN.2021.3102382 ↗
62. 10.1088/2053-1591/ab1bc310.1088/2053-1591/ab1bc3 ↗
63. 10.1016/j.snb.2019.01.03710.1016/j.snb.2019.01.037 ↗
64. 10.1021/acsami.9b2209810.1021/acsami.9b22098 ↗
65. 10.1016/j.snb.2010.04.00310.1016/j.snb.2010.04.003 ↗
66. 10.1016/j.apsusc.2022.15533710.1016/j.apsusc.2022.155337 ↗
67. 10.1016/j.snb.2022.13170310.1016/j.snb.2022.131703 ↗
68. 10.1039/C9TA07855J10.1039/C9TA07855J ↗
69. 10.1109/LED.2020.298794810.1109/LED.2020.2987948 ↗
70. 10.1002/smll.20170397410.1002/smll.201703974 ↗
71. 10.1016/j.jallcom.2019.03.12410.1016/j.jallcom.2019.03.124 ↗
72. 10.1002/crat.20200015510.1002/crat.202000155 ↗
73. 10.1016/j.jallcom.2022.16578810.1016/j.jallcom.2022.165788 ↗
74. 10.1016/j.electacta.2022.14086310.1016/j.electacta.2022.140863 ↗
75. 10.1016/j.snb.2022.13265410.1016/j.snb.2022.132654 ↗
76. 10.1002/adfm.20211334810.1002/adfm.202113348 ↗
77. 10.3390/s2106195810.3390/s21061958 ↗
78. 10.1002/sstr.20210002810.1002/sstr.202100028 ↗
79. 10.1016/j.apsusc.2015.01.02010.1016/j.apsusc.2015.01.020 ↗
80. 10.1039/D1TC05835E10.1039/D1TC05835E ↗
81. 10.1016/j.jallcom.2019.05.11110.1016/j.jallcom.2019.05.111 ↗
82. 10.3390/s2106210310.3390/s21062103 ↗
83. 10.1016/j.jcis.2017.11.07310.1016/j.jcis.2017.11.073 ↗
84. 10.1039/C9CE00710E10.1039/C9CE00710E ↗
85. 10.1039/D0QI00134A10.1039/D0QI00134A ↗
86. 10.1021/acsami.8b1125410.1021/acsami.8b11254 ↗
87. 10.1016/j.apsusc.2019.14482110.1016/j.apsusc.2019.144821 ↗
88. 10.1016/j.nanoen.2016.11.01810.1016/j.nanoen.2016.11.018 ↗
89. 10.1016/j.nanoen.2018.02.00710.1016/j.nanoen.2018.02.007 ↗
90. 10.1021/acsami.6b1324410.1021/acsami.6b13244 ↗
91. 10.1016/j.nanoen.2018.12.01110.1016/j.nanoen.2018.12.011 ↗
92. 10.1016/j.jcis.2021.11.11610.1016/j.jcis.2021.11.116 ↗
93. 10.1049/hve.2019.017010.1049/hve.2019.0170 ↗
94. 10.1021/acsami.2c0234010.1021/acsami.2c02340 ↗
95. 10.1111/j.1365-2702.2004.01076.x10.1111/j.1365-2702.2004.01076.x ↗
96. 10.1016/j.agee.2022.10794610.1016/j.agee.2022.107946 ↗
97. 10.1002/advs.20160040410.1002/advs.201600404 ↗