Porosimetry for Thin Films of Metal–Organic Frameworks: A Comparison of Positron Annihilation Lifetime Spectroscopy and Adsorption‐Based Methods
Source abstract
Abstract
Abstract Thin films of crystalline and porous metal–organic frameworks (MOFs) have great potential in membranes, sensors, and microelectronic chips. While the morphology and crystallinity of MOF films can be evaluated using widely available techniques, characterizing their pore size, pore volume, and specific surface area is challenging due to the low amount of material and substrate effects. Positron annihilation lifetime spectroscopy (PALS) is introduced as a powerful method to obtain pore size information and depth profiling in MOF films. The complementarity of this approach to established physisorption‐based methods such as quartz crystal microbalance (QCM) gravimetry, ellipsometric porosimetry (EP), and Kr physisorption (KrP) is illustrated. This comprehensive discussion on MOF thin film porosimetry is supported by experimental data for thin films of ZIF‐8.
Source: crossref · Quality: baseline
Research context
OpenAlex topics: Metal-Organic Frameworks: Synthesis and Applications · Muon and positron interactions and applications · Chemical Synthesis and Characterization
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
Affiliations
Centre for Membrane Separations, Adsorption Catalysis and Spectroscopy for Sustainable Solutions (cMACS) KU Leuven Celestijnenlaan 200F, Box 2454 Leuven 3001 Belgium
Institut für Angewandte Physik und Messtechnik LRT2 Universität der Bundeswehr München Werner‐Heisenberg‐Weg 39 Neubiberg 85577 Germany
Heinz Maier Leibnitz Zentrum (MLZ) Technische Universität München Lichtenbergstraße 1 Garching 85748 Germany
Institute for Integrated Cell‐Material Sciences (WPI‐iCeMS) Kyoto University iCeMS Research Building, Yoshida, Sakyo‐ku Kyoto 606‐8501 Japan
Aix Marseille Université Université de Toulon CNRS IM2NP Marseille 13397 France
Institute of Separation Science and Technology Department of Chemical and Bioengineering University of Erlangen‐Nuremberg Egerlandstrasse 3 Erlangen 91058 Germany
Funding
European Research Council
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