Atomic Layer Coated Al₂O₃ on Nitrogen Doped Vertical Graphene Nanosheets for High Performance Sodium Ion Batteries

Heteroatom doped graphene materials are considered as promising anode for high‐performance sodium‐ion batteries (SIBs). Defective and porous structure especially with large specific surface area is generally considered as a feasible strategy to boost reaction kinetics; however, the unwanted side reaction at the anode hinders the practical application of SIBs. In this work, a precisely controlled Al₂O₃ coated nitrogen doped vertical graphene nanosheets (NVG) anode material has been proposed, which exhibits excellent sodium storage capacity and cycling stability. The ultrathin Al₂O₃ coating on the NVG is considered to help construct an advantageous interface between electrode and electrolyte, both alleviating the electrolyte decomposition and enhancing sodium adsorption ability. As a result, the optimal Al₂O₃ coated NVG materials delivers a high reversible capacity (835.0 mAh g⁻¹) and superior cycling stability (retention of 92.3% after 5000 cycles). This work demonstrates a new way to design graphene‐based anode materials for high‐performance sodium‐ion batteries.