DataVXAdvanced MaterialsPaper
journal article·2023-04Open access

Spacer‐Engineered Ionic Channels in Covalent Organic Framework Membranes toward Ultrafast Proton Transport

Benbing Shi, Xiao Pang, Bohui Lyu, Hong Wu, Jianliang Shen, Jingyuan Guan, Xiaoyao Wang, Chunyang Fan, Li Cao, Tianhao Zhu, Yan Kong, Yawei Liu, Zhongyi Jiang

Advanced Materials· Volume 35· Issue 16
Publisher pageOpen full text
Source abstract

Abstract

Abstract Side‐chain engineering of covalent organic frameworks as advanced ion conductors is a critical issue to be explored. Herein, ionic covalent organic framework membranes (iCOFMs) with spacer‐engineered ionic channel are de novo designed and prepared. The ionic channels are decorated with side chains comprising spacers having different carbon chain lengths and the –SO3H groups at the end. Attributed to the synergistic contribution from the spacers and the –SO3H groups, the iCOFM with moderate‐length spacer exhibit the highest through‐plane proton conductivity of 889 mS cm‐1 at 90 °C.
Source: crossref · Quality: baseline

Research context

OpenAlex topics: Covalent Organic Framework Applications · Fuel Cells and Related Materials · Metal-Organic Frameworks: Synthesis and Applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Key Laboratory for Green Chemical Technology of Ministry of Education School of Chemical Engineering and Technology Tianjin University Tianjin 300072 China

Haihe Laboratory of Sustainable Chemical Transformations Tianjin 300192 China

Beijing Key Laboratory of Ionic Liquids Clean Process CAS Key Laboratory of Green Process and Engineering State Key Laboratory of Multiphase Complex Systems Institute of Process Engineering Chinese Academy of Sciences Beijing 100190 China

Joint School of National University of Singapore and Tianjin University International Campus of Tianjin University Binhai New City Fuzhou 350207 China

Zhejiang Institute of Tianjin University Ningbo Zhejiang 315201 China

Funding

National Natural Science Foundation of China

References (49)

Show source-provided references
1. 10.1038/nature0653110.1038/nature06531 ↗
2. 10.1038/nature0392110.1038/nature03921 ↗
3. 10.1038/s41586-021-03482-710.1038/s41586-021-03482-7 ↗
4. 10.1126/science.107257410.1126/science.1072574 ↗
5. 10.1126/science.aah349710.1126/science.aah3497 ↗
6. 10.1038/s41586-019-1881-010.1038/s41586-019-1881-0 ↗
7. 10.1038/nature0641710.1038/nature06417 ↗
8. 10.1038/s41560-018-0261-610.1038/s41560-018-0261-6 ↗
9. 10.1038/s41467-020-16977-010.1038/s41467-020-16977-0 ↗
10. 10.1021/jacs.5b1349010.1021/jacs.5b13490 ↗
11. 10.1002/anie.20210410610.1002/anie.202104106 ↗
12. 10.1021/jacs.8b0767010.1021/jacs.8b07670 ↗
13. 10.1038/s41467-020-15918-110.1038/s41467-020-15918-1 ↗
14. 10.1021/jacs.7b0518210.1021/jacs.7b05182 ↗
15. 10.1021/jacs.2c0042910.1021/jacs.2c00429 ↗
16. 10.1002/anie.20191257910.1002/anie.201912579 ↗
17. 10.1021/jacs.9b0244810.1021/jacs.9b02448 ↗
18. 10.1002/marc.20220067810.1002/marc.202200678 ↗
19. 10.1021/jacs.9b0608010.1021/jacs.9b06080 ↗
20. 10.1021/jacs.8b1355110.1021/jacs.8b13551 ↗
21. 10.1039/D1CE00957E10.1039/D1CE00957E ↗
22. 10.1002/anie.20211069510.1002/anie.202110695 ↗
23. 10.1002/adma.20200128410.1002/adma.202001284 ↗
24. 10.1039/D1TA10431D10.1039/D1TA10431D ↗
25. 10.1016/j.apsusc.2022.15436310.1016/j.apsusc.2022.154363 ↗
26. 10.1021/acsaem.8b0029410.1021/acsaem.8b00294 ↗
27. 10.1021/jp300040w10.1021/jp300040w ↗
28. 10.1016/j.memsci.2021.11909610.1016/j.memsci.2021.119096 ↗
29. 10.1002/adma.20200556510.1002/adma.202005565 ↗
30. 10.1038/s41467-022-33868-810.1038/s41467-022-33868-8 ↗
31. 10.1002/anie.20210519010.1002/anie.202105190 ↗
32. 10.3390/ma1111233510.3390/ma11112335 ↗
33. 10.1016/j.memsci.2021.11944010.1016/j.memsci.2021.119440 ↗
34. 10.1002/anie.20211766110.1002/anie.202117661 ↗
35. 10.1002/jccs.20190036310.1002/jccs.201900363 ↗
36. 10.1126/science.abe195110.1126/science.abe1951 ↗
37. 10.1038/s41560-017-0018-710.1038/s41560-017-0018-7 ↗
38. 10.1002/anie.20160904910.1002/anie.201609049 ↗
39. 10.1038/s41467-021-23721-910.1038/s41467-021-23721-9 ↗
40. 10.1021/j100389a01010.1021/j100389a010 ↗
41. 10.1021/j100161a07010.1021/j100161a070 ↗
42. 10.1002/jcc.2105710.1002/jcc.21057 ↗
43. 10.1038/nmeth.406710.1038/nmeth.4067 ↗
44. 10.1021/ci300363c10.1021/ci300363c ↗
45. 10.1021/ci300364910.1021/ci3003649 ↗
46. 10.1021/ct100125x10.1021/ct100125x ↗
47. 10.1016/j.memsci.2022.12075410.1016/j.memsci.2022.120754 ↗
48. 10.1063/1.168307510.1063/1.1683075 ↗
49. 10.1002/jcc.2029110.1002/jcc.20291 ↗