journal article·2020-10

A Phenol‐Amine Superglue Inspired by Insect Sclerotization Process

Younseon Wang, Eun Je Jeon, Jeehee Lee, Honggu Hwang, Seung‐Woo Cho, Haeshin Lee

Advanced Materials· Volume 32· Issue 43
Publisher page

Abstract

Abstract Exoskeletons of insects formed by sclerotization processes exhibit superstrong properties in moduli. Here, it is demonstrated that mimicking the sclerotization process using phenol and polyamine molecules unexpectedly results in a 100% ecofriendly, biocompatible waterborne superglue. Oxygen presented in air and dissolved in water acts as an initiator producing phenolic radical/quinone for superglue curing. Despite synthesis‐free uses of water, phenol, and polyamine, its adhesion strength is comparable to commercial epoxy glue showing >6 MPa in lap shear strength. The phenol‐amine superglue bonds to various substrates including ceramics, woods, fabrics, plastics, metals, and importantly biological tissues. Due to strong adhesion, the superglue effectively seals wounds within a few seconds, and, due to its waterborne nature, no harmful respiratory effect is observed because of any release of volatile organic compounds. The easy, cost‐effective preparation of the phenol‐amine superglue can revolutionize varieties of industrial, biomedical, daily life processes.
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Research context

OpenAlex topics: Polymer Surface Interaction Studies · Tribology and Wear Analysis · biodegradable polymer synthesis and properties

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Department of Chemistry Korea Advanced Institute of Science and Technology (KAIST) 291 University Rd. Daejeon 34141 Republic of Korea

Department of Biotechnology Yonsei University 50 Yonsei‐ro Seoul 03722 Republic of Korea

Department of Biomaterials Science and Engineering Yonsei University 50 Yonsei‐ro Seoul 03722 Republic of Korea

Graduate School of Medical Science and Engineering Korea Advanced Institute of Science and Technology (KAIST) 291 University Rd. Daejeon 34141 Republic of Korea

KONON Advanced Research Cluster KOLON One&Only Tower 110 Magokdong‐ro Seoul 07793 Republic of Korea

Center for Nanomedicine Institute for Basic Science (IBS) 50 Yonsei‐ro Seoul 03722 Republic of Korea

Graduate Program of Nano Biomedical Engineering (NanoBME) Advanced Science Institute Yonsei University 50 Yonsei‐ro Seoul 03722 Republic of Korea

Funding

National Research Foundation of Korea · Institute for Basic Science · Ministry of Education, Science and Technology

References (29)

Show source-provided references
1. 10.1126/science.aab055610.1126/science.aab0556 ↗
2. 10.1126/science.114724110.1126/science.1147241 ↗
3. 10.1146/annurev-matsci-062910-10042910.1146/annurev-matsci-062910-100429 ↗
4. 10.1002/adfm.20190302210.1002/adfm.201903022 ↗
5. 10.1002/adfm.20150000610.1002/adfm.201500006 ↗
6. 10.1039/C7TB00813A10.1039/C7TB00813A ↗
7. 10.1039/C7CC07215E10.1039/C7CC07215E ↗
8. 10.1016/j.actbio.2015.03.03110.1016/j.actbio.2015.03.031 ↗
9. 10.1021/acs.biomac.7b0092110.1021/acs.biomac.7b00921 ↗
10. 10.1002/adfm.20130353610.1002/adfm.201303536 ↗
11. 10.1039/C5CC00101C10.1039/C5CC00101C ↗
12. 10.1038/nature1280610.1038/nature12806 ↗
13. 10.1126/science.aah636210.1126/science.aah6362 ↗
14. 10.1016/j.ibmb.2009.10.00710.1016/j.ibmb.2009.10.007 ↗
15. 10.1021/acs.chemmater.5b0168010.1021/acs.chemmater.5b01680 ↗
16. 10.1016/j.asd.2004.05.00610.1016/j.asd.2004.05.006 ↗
17. 10.1002/adma.20160329010.1002/adma.201603290 ↗
18. 10.1038/s41551-018-0227-910.1038/s41551-018-0227-9 ↗
19. 10.1002/anie.20160166710.1002/anie.201601667 ↗
20. 10.1002/admi.20140011310.1002/admi.201400113 ↗
21. 10.1021/ma070356w10.1021/ma070356w ↗
22. 10.1007/s11051-009-9731-x10.1007/s11051-009-9731-x ↗
23. 10.1016/j.jaci.2016.05.01110.1016/j.jaci.2016.05.011 ↗
24. Ramos F. L. · Int. J. Chronic Obstruct. Pulm. Dis. · 2014 · 9 · 139
25. 10.1136/thx.2003.01368010.1136/thx.2003.013680 ↗
26. 10.1016/j.compositesb.2008.01.00210.1016/j.compositesb.2008.01.002 ↗
27. 10.1063/1.314802610.1063/1.3148026 ↗
28. 10.1126/science.271.5248.48210.1126/science.271.5248.482 ↗
29. 10.1016/j.bjps.2008.03.02210.1016/j.bjps.2008.03.022 ↗