journal article·2015-04

Thiofluorographene–Hydrophilic Graphene Derivative with Semiconducting and Genosensing Properties

Veronika Urbanová, Kateřina Holá, Athanasios B. Bourlinos, Klára Čépe, Adriano Ambrosi, Adeline Huiling Loo, Martin Pumera, František Karlický, Michal Otyepka, Radek Zbořil

Advanced Materials· Volume 27· Issue 14
Publisher page

Abstract

We present the first example of covalent chemistry on fluorographene, enabling the attachment of -SH groups through nucleophilic substitution of fluorine in a polar solvent. The resulting thiographene-like, 2D derivative is hydrophilic with semiconducting properties and bandgap between 1 and 2 eV depending on F/SH ratio. Thiofluorographene is applied in DNA biosensing by electrochemical impedance spectroscopy.
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Research context

OpenAlex topics: Advanced biosensing and bioanalysis techniques · Molecular Junctions and Nanostructures · Graphene research and applications

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Affiliations

Regional Centre of Advanced Technologies and Materials Department of Physical Chemistry, Faculty of Science Palacky University Slechtitelu 11 783 71 Olomouc Czech Republic

Physics Department University of Ioannina Ioannina 45110 Greece

School of Physical and Mathematical Science Division of Chemistry and Biological Chemistry Nanyang Technological University 21 Nanyang Link Singapore

References (42)

Show source-provided references
1. 10.1126/science.110289610.1126/science.1102896 ↗
2. 10.1126/science.115887710.1126/science.1158877 ↗
3. 10.1002/adma.20120158710.1002/adma.201201587 ↗
4. 10.2217/nnm.10.15810.2217/nnm.10.158 ↗
5. 10.1016/j.trac.2012.02.01110.1016/j.trac.2012.02.011 ↗
6. 10.1016/j.tibtech.2014.04.00410.1016/j.tibtech.2014.04.004 ↗
7. 10.1039/C2CS35342C10.1039/C2CS35342C ↗
8. 10.1016/j.trac.2010.05.01110.1016/j.trac.2010.05.011 ↗
9. 10.1002/anie.20090167810.1002/anie.200901678 ↗
10. 10.1021/nn901317d10.1021/nn901317d ↗
11. 10.1039/c3cs60132c10.1039/c3cs60132c ↗
12. 10.1002/adma.20090368910.1002/adma.200903689 ↗
13. 10.1021/nn402402710.1021/nn4024027 ↗
14. 10.1002/smll.20100140110.1002/smll.201001401 ↗
15. 10.1021/nl101437p10.1021/nl101437p ↗
16. 10.1103/PhysRevB.82.19543610.1103/PhysRevB.82.195436 ↗
17. 10.1063/1.473699810.1063/1.4736998 ↗
18. 10.1038/nphys218310.1038/nphys2183 ↗
19. 10.1021/ct400476r10.1021/ct400476r ↗
20. 10.1021/cr300041210.1021/cr3000412 ↗
21. 10.1039/c1jm13228h10.1039/c1jm13228h ↗
22. 10.1002/smll.20100155510.1002/smll.201001555 ↗
23. 10.1002/chem.20140213210.1002/chem.201402132 ↗
24. 10.1021/nn401296b10.1021/nn401296b ↗
25. 10.1021/nn203393d10.1021/nn203393d ↗
26. 10.1021/ac100036p10.1021/ac100036p ↗
27. 10.1002/anie.20140400210.1002/anie.201404002 ↗
28. 10.1002/anie.20140278010.1002/anie.201402780 ↗
29. 10.1016/B978-0-08-057116-4.50020-110.1016/B978-0-08-057116-4.50020-1 ↗
30. Table of Interatomic Distances and Configuration of Molecules and Ions Special Publication No 11; Supplement 1956–1959 Special Publication No 18 Chemical Society London 1958 196.
31. 10.1063/1.240466310.1063/1.2404663 ↗
32. 10.1002/andp.20140009510.1002/andp.201400095 ↗
33. 10.1016/S0925-4005(00)00468-810.1016/S0925-4005(00)00468-8 ↗
34. 10.1016/j.aca.2010.08.02210.1016/j.aca.2010.08.022 ↗
35. 10.1021/nn200091p10.1021/nn200091p ↗
36. 10.1021/la048083a10.1021/la048083a ↗
37. 10.1038/nbt.242110.1038/nbt.2421 ↗
38. 10.1002/elan.20039011410.1002/elan.200390114 ↗
39. 10.1021/ac031397310.1021/ac0313973 ↗
40. 10.1016/j.bios.2004.06.03910.1016/j.bios.2004.06.039 ↗
41. 10.1039/b305798b10.1039/b305798b ↗
42. 10.1016/j.elecom.2012.12.01010.1016/j.elecom.2012.12.010 ↗