journal article·2019-04

Progressively Exposing Active Facets of 2D Nanosheets toward Enhanced Pseudocapacitive Response and High‐Rate Sodium Storage

Xin Xu, Ruisheng Zhao, Bo Chen, Lishu Wu, Chenji Zou, Wei Ai, Hua Zhang, Wei Huang, Ting Yu

Advanced Materials· Volume 31· Issue 17
Publisher page

Abstract

Abstract Sodium‐ion batteries are gradually regarded as a prospective alternative to lithium‐ion batteries due to the cost consideration. Here, three kinds of tin (IV) sulfide nanosheets are controllably designed with progressively exposed active facets, leading to beneficial influences on the Na + storage kinetics, resulting in gradient improvements of pseudocapacitive response and rate performance. Interestingly, different forms of kinetics results are generated accompanying with the morphology and structure evolution of the three nanosheets. Finally, detailed density functional theory simulations are also applied to analyze the above experimental achievements, proving that different exposed facets of crystalline anodes possess dissimilar Na + storage kinetics. The investigation experiences and conclusions shown in this work are meaningful to explore many other proper structure design routes toward the high‐rate and stable metal‐ions storage.
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Research context

OpenAlex topics: Advancements in Battery Materials · Supercapacitor Materials and Fabrication · Advanced Battery Materials and Technologies

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Shaanxi Institute of Flexible Electronics (SIFE) Northwestern Polytechnical University (NPU) Xi'an 710072 China

Division of Physics and Applied Physics School of Physical and Mathematical Sciences Nanyang Technological University Singapore 637371 Singapore

Department of Applied Chemistry School of Science Xi'an Jiaotong University Xi'an 710049 China

School of Materials Science and Engineering Nanyang Technological University Singapore 639798 Singapore

Key Laboratory of Flexible Electronics (KLOFE) & Institute of Advanced Materials (IAM) Nanjing Tech University (NanjingTech) Nanjing 211800 China

Funding

Ministry of Education of the People's Republic of China · National Basic Research Program of China · Natural Science Foundation of Jiangsu Province · National Natural Science Foundation of China · Nantong University · Joint Research Fund for Overseas Chinese Scholars and Scholars in Hong Kong and Macao

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