DataVXAdvanced MaterialsPaper
journal article·2018-10

Construction of Porous Aromatic Frameworks with Exceptional Porosity via Building Unit Engineering

Meiping Li, Hao Ren, Fuxing Sun, Yuyang Tian, Youliang Zhu, Jialu Li, Xin Mu, Jun Xu, Feng Deng, Guangshan Zhu

Advanced Materials· Volume 30· Issue 43
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Source abstract

Abstract

Abstract The construction of excellent porous organic frameworks (POFs) with high surface areas and stability is always a tremendous challenge in synthetic chemistry. The geometric configuration and reactive group of building unit are crucial factors to influence the structure and porosity of the resulting product. Herein, the design, synthesis, and characterization of two porous aromatic framework (PAF) materials, named PAF‐100 and PAF‐101, are reported via a strategy of building unit engineering. PAF‐100 and PAF‐101 present high Brunauer–Emmett–Teller surface areas exceeding 5000 m2 g−1 and uniform pore size distributions. Furthermore, PAF‐100 and PAF‐101 show high methane uptake with value of 742 and 622 cm3 g−1, respectively, at 298 K and 70 bar. The successful synthesis of PAFs with exceptional porosity from engineered building unit is powerful for constructing highly porous POFs.
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Research context

OpenAlex topics: Metal-Organic Frameworks: Synthesis and Applications · Covalent Organic Framework Applications · Membrane Separation and Gas Transport

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

State Key Laboratory of Inorganic Synthesis and Preparative Chemistry Jilin University Changchun 130012 China

Key Laboratory of Polyoxometalate Science of the Ministry of Education Faculty of Chemistry Northeast Normal University Changchun 130024 China

State Key Laboratory of Polymer Physics and Chemistry Changchun Institute of Applied Chemistry Chinese Academy of Sciences Changchu 130022 China

State Key Laboratory of Magnetic Resonance and Atomic and Molecular Physics National Center for Magnetic Resonance in Wuhan Wuhan Institute of Physics and Mathematics Chinese Academy of Sciences Wuhan 430071 China

Funding

National Natural Science Foundation of China · Major International Joint Research Programme

References (43)

Show source-provided references
1. 10.1126/science.aaa807510.1126/science.aaa8075 ↗
2. 10.1002/adma.20170075010.1002/adma.201700750 ↗
3. 10.1007/978-3-662-45456-510.1007/978-3-662-45456-5 ↗
4. 10.1038/4624810.1038/46248 ↗
5. 10.1002/anie.20030061010.1002/anie.200300610 ↗
6. 10.1039/B618320B10.1039/B618320B ↗
7. 10.1039/C7CS90049J10.1039/C7CS90049J ↗
8. 10.1021/cr200440z10.1021/cr200440z ↗
9. 10.1021/acs.chemrev.6b0043910.1021/acs.chemrev.6b00439 ↗
10. 10.1016/j.progpolymsci.2011.09.00210.1016/j.progpolymsci.2011.09.002 ↗
11. 10.1016/j.ccr.2015.12.01010.1016/j.ccr.2015.12.010 ↗
12. 10.1039/c2cs35157a10.1039/c2cs35157a ↗
13. 10.1039/C2CS35072F10.1039/C2CS35072F ↗
14. 10.1002/adma.20100244010.1002/adma.201002440 ↗
15. 10.1021/ja305563910.1021/ja3055639 ↗
16. 10.1021/acscentsci.7b0018610.1021/acscentsci.7b00186 ↗
17. 10.1021/jacs.7b0216110.1021/jacs.7b02161 ↗
18. 10.1021/jacs.8b0031310.1021/jacs.8b00313 ↗
19. 10.1021/cr500258910.1021/cr5002589 ↗
20. 10.1002/adma.20170430310.1002/adma.201704303 ↗
21. 10.1126/science.113991510.1126/science.1139915 ↗
22. 10.1021/jacs.6b1031610.1021/jacs.6b10316 ↗
23. 10.1021/ja203807h10.1021/ja203807h ↗
24. 10.1021/ma100639610.1021/ma1006396 ↗
25. 10.1039/C6CS00851H10.1039/C6CS00851H ↗
26. 10.1002/anie.20090463710.1002/anie.200904637 ↗
27. 10.1002/anie.20090682710.1002/anie.200906827 ↗
28. 10.1039/C4MH00163J10.1039/C4MH00163J ↗
29. 10.1039/c1ee01222c10.1039/c1ee01222c ↗
30. 10.1002/adma.20110175910.1002/adma.201101759 ↗
31. 10.1039/C5CC01828E10.1039/C5CC01828E ↗
32. Kizzie1 A. C. · Mater. Sci. Appl. · 2014 · 5 · 387
33. 10.1039/c3cc00039g10.1039/c3cc00039g ↗
34. 10.1021/ja208777310.1021/ja2087773 ↗
35. 10.1039/C1CE06091K10.1039/C1CE06091K ↗
36. 10.1039/C2CE25409C10.1039/C2CE25409C ↗
37. 10.1021/cg500158c10.1021/cg500158c ↗
38. 10.1002/jcc.2449510.1002/jcc.24495 ↗
39. 10.1080/00268976.2018.143490410.1080/00268976.2018.1434904 ↗
40. 10.1126/science.119216010.1126/science.1192160 ↗
41. 10.1021/jacs.7b0834710.1021/jacs.7b08347 ↗
42. 10.1002/adma.20170479210.1002/adma.201704792 ↗
43. 10.1016/j.chempr.2016.09.00910.1016/j.chempr.2016.09.009 ↗