journal article·2014-09

Increasing the Maximum Achievable Strain of a Covalent Polymer Gel Through the Addition of Mechanically Invisible Cross‐Links

Zachary S. Kean, Jennifer L. Hawk, Shaoting Lin, Xuanhe Zhao, Rint P. Sijbesma, Stephen L. Craig

Advanced Materials· Volume 26· Issue 34
Publisher page

Abstract

Hydrogels and organogels made from polymer networks are widely used in biomedical applications and soft, active devices for which the ability to sustain large deformations is required. The strain at which polymer networks fracture is typically improved through the addition of elements that dissipate energy, but these materials require extra work to achieve a given, desired level of deformation. Here, the addition of mechanically "invisible" supramolecular crosslinks causes substantial increases in the ultimate gel properties without incurring the added energetic costs of dissipation.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: Hydrogels: synthesis, properties, applications · Supramolecular Self-Assembly in Materials · Polymer composites and self-healing

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Department of Chemistry Duke University Durham NC 27708–0346 USA

Soft Active Materials Lab Department of Mechanical Engineering and Materials Science Duke University Durham NC 27708 USA

Laboratory of Macromolecular and Organic Chemistry and the Institute for Complex Molecular Systems Eindhoven University of Technology Eindhoven The Netherlands

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