journal article·2020-11Open access

Recent Advances of Solid‐State NMR Spectroscopy for Microporous Materials

Shenhui Li, Olivier Lafon, Weiyu Wang, Qiang Wang, Xingxing Wang, Yi Li, Jun Xu, Feng Deng

Advanced Materials· Volume 32· Issue 44

Abstract

Abstract Microporous materials have attracted a rapid growth of research interest in materials science and the multidisciplinary area because of their wide applications in catalysis, separation, ion exchange, gas storage, drug release, and sensing. A fundamental understanding of their diverse structures and properties is crucial for rational design of high‐performance materials and technological applications in industry. Solid‐state NMR (SSNMR), capable of providing atomic‐level information on both structure and dynamics, is a powerful tool in the scientific exploration of solid materials. Here, advanced SSNMR instruments and methods for characterization of microporous materials are briefly described. The recent progress of the application of SSNMR for the investigation of microporous materials including zeolites, metal–organic frameworks, covalent organic frameworks, porous aromatic frameworks, and layered materials is discussed with representative work. The versatile SSNMR techniques provide detailed information on the local structure, dynamics, and chemical processes in the confined space of porous materials. The challenges and prospects in SSNMR study of microporous and related materials are discussed.
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Research context

OpenAlex topics: Advanced NMR Techniques and Applications · Covalent Organic Framework Applications · Metal-Organic Frameworks: Synthesis and Applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

National Centre for Magnetic Resonance in Wuhan State Key Laboratory of Magnetic Resonance and Atomic and Molecular Physics Innovation Academy for Precision Measurement Science and Technology Chinese Academy of Sciences Wuhan 430071 China

University of Chinese Academy of Sciences Beijing 100049 China

Univ. Lille CNRS Centrale Lille Univ. Artois UMR 8181– UCCS – Unité de Catalyse et Chimie du Solide Lille F‐59000 France

Institut Universitaire de France Paris 75231 France

State Key Laboratory of Inorganic Synthesis and Preparative Chemistry College of Chemistry Jilin University 2699 Qianjin Street Changchun 130012 China

International Center of Future Science Jilin University Changchun 130012 China

Wuhan National Laboratory for Optoelectronics Huazhong University of Science and Technology Wuhan 430074 China

Funding

National Natural Science Foundation of China · Chinese Academy of Sciences · Natural Science Foundation of Hubei Province · Higher Education Discipline Innovation Project

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