journal article·2014-05

Spectroscopic Proof of the Correlation between Redox‐State and Charge‐Carrier Transport at the Interface of Resistively Switching Ti/PCMO Devices

Anja Herpers, Christian Lenser, Chanwoo Park, Francesco Offi, Francesco Borgatti, Giancarlo Panaccione, Stephan Menzel, Rainer Waser, Regina Dittmann

Advanced Materials· Volume 26· Issue 17
Publisher page

Abstract

By using hard X-ray photoelectron spectroscopy experimentally, proof is provided that resistive switching in Ti/Pr₀.₄₈ Ca₀.₅₂ MnO₃ (PCMO) devices is based on a redox-process that mainly occurs on the Ti-side. The different resistance states are determined by the amount of fully oxidized Ti-ions in the stack, implying a reversible redox-reaction at the interface, which governs the formation and shortening of an insulating tunnel barrier.
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Research context

OpenAlex topics: Advanced Memory and Neural Computing · Transition Metal Oxide Nanomaterials · Electronic and Structural Properties of Oxides

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Peter Grünberg Institute Research Center Jülich 52425 Germany

CNISM and Dipartimento di Scienze Universita Roma Tre Rome Italy

CNR – Istituto per lo Studio dei Materiali Nanostrutturati (ISMN) via P. Gobetti 101 I‐40129 Bologna Italy

CNR – Istituto Officina dei Materiali (IOM) Laboratorio TASC S.S.14, Km 163.5 I‐34149 Trieste Italy

Funding

European Union Council · Federal Ministry of Education and Research (BMBF)

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