Diatomite‐Templated Synthesis of Single‐Atom Cobalt‐Doped MoS₂/Carbon Composites to Boost Sodium Storage

Abstract 2D transition metal dichalcogenides (TMDCs) and single‐atom catalysts (SACs) are promising electrodes for energy conversion/storage because of the layered structure and maximum atom utilization efficiency. However, the integration of such two type materials and the relevant sodium storage applications remain daunting challenges. Here, an ingenious diatomite‐templated synthetic strategy is designed to fabricate single‐atom cobalt‐doped MoS₂/carbon (SA Co‐MoS₂/C) composites toward the high‐performance sodium storage. Benefiting from the unique hierarchical structure, high electron/sodium‐ion conductivity, and abundant active sites, the obtained SA Co‐MoS₂/C reveals remarkable specific capacity (≈604.0 mAh g⁻¹ at 0.1 A g⁻¹), high rate performance, and outstanding long cyclic stability. Particularly, the sodium‐ion full cell composed of SA Co‐MoS₂/C anode and Na₃V₂(PO₄)₃ cathode demonstrates unexpected stability with the cycle number exceeded 1200. The internal sodium storage mechanism is clarified with the aid of density functional theory calculations and in situ experimental characterizations. This work not only represents a substantial leap in terms of synthesizing SACs on 2D TMDCs but also provides a crucial step toward the practical sodium‐ion battery applications.