journal article·2024-05

Near‐Zero Energy Consumption Capacitors by Controlling Inhomogeneous Polarization Configuration

Liang Chen, Tengfei Hu, Xiaoming Shi, Huifen Yu, Hao Zhang, Jie Wu, Zhengqian Fu, He Qi, Jun Chen

Advanced Materials· Volume 36· Issue 21
Publisher page

Abstract

Abstract Taking into account the need for energy conservation, achieving near‐zero energy loss, namely ultrahigh efficiency (η), in energy storage capacitors with large recoverable energy storage density (Wrec) plays an important role in applications, which is one of the major challenges in dielectric energy storage field. Here, guided by phase‐field simulation, inhomogeneous polarization configuration with multiple symmetries and polarization magnitudes is controlled through aliovalent strongly polar double ion design to establish a strongly disordered state. A record‐high η of ≈97.4% is realized in lead‐free relaxors with a large Wrec of ≈8.6 J cm−3, which also give a giant Wrec of ≈11.6 J cm−3 with an ultrahigh η of ≈96.1% through high‐energy ball milling, showing a breakthrough progress in ceramic capacitors with a maximum figure of merit of 330. This work demonstrates that controlling inhomogeneous polarization configuration is an effective avenue to develop new high‐performance near‐zero energy loss energy storage capacitors.
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Research context

OpenAlex topics: Ferroelectric and Piezoelectric Materials · Acoustic Wave Resonator Technologies · Multiferroics and related materials

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Beijing Advanced Innovation Center for Materials Genome Engineering Department of Physical Chemistry University of Science and Technology Beijing Beijing 100083 China

State Key Laboratory of High Performance Ceramics and Superfine Microstructures and Key Laboratory of Inorganic Functional Materials and Devices Shanghai Institute of Ceramics Chinese Academy of Sciences Shanghai 200050 China

School of Mathematics and Physics University of Science and Technology Beijing Beijing 100083 China

Hainan University Haikou Hainan Province 570228 China

Funding

National Natural Science Foundation of China · China Postdoctoral Science Foundation · National Postdoctoral Program for Innovative Talents · Fundamental Research Funds for the Central Universities · National Key Research and Development Program of China

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