P2‐Na_2/3Ni_2/3Te_1/3O₂ Cathode for Na‐ion Batteries with High Voltage and Excellent Stability

Air‐stable layered structured cathodes with high voltage and good cycling stability are highly desired for the practical application of Na‐ion batteries. Herein, we report a P2‐Na_2/3Ni_2/3Te_1/3O₂ cathode that is stable in ambient air with an average operating voltage of ~3.8 V, demonstrating excellent cycling stability with a capacity retention of more than 92.7% after 500 cycles at 20 mA g⁻¹ and good rate capability with 91.9% capacity utilization at 500 mA g⁻¹ with respect to capacity at 5 mA g⁻¹ between 2.0 and 4.0 V. When the upper cutoff voltage is increased to 4.4 V, P2‐Na_2/3Ni_2/3Te_1/3O₂ delivers a reversible capacity of 71.9 mAh g⁻¹ and retains 91.8% of the capacity after 100 cycles at 20 mA g⁻¹. The charge compensation during charge/discharge is mainly due to the redox couple of Ni²⁺/Ni³⁺ in the host with a small amount of contribution from oxygen. The stable structure of the material without phase transformation and with small volume change during charge‐discharge allows it to give excellent cycle performance especially when the upper cutoff voltage is not higher than 4.2 V.