journal article·2015-12

A Cofacially Stacked Electron‐Deficient Small Molecule with a High Electron Mobility of over 10 cm2 V−1 s−1 in Air

Jin‐Hu Dou, Yu‐Qing Zheng, Ze‐Fan Yao, Ting Lei, Xingxing Shen, Xu‐Yi Luo, Zhi‐Ao Yu, Shi‐Ding Zhang, Guangchao Han, Zhi Wang, Yuanping Yi, Jie‐Yu Wang, Jian Pei

Advanced Materials· Volume 27· Issue 48
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Abstract

A strong, electron-deficient small molecule, F4-BDOPV, has a lowest unoccupied molecular orbital (LUMO) level down to -4.44 eV and exhibits cofacial packing in single crystals. These features provide F4-BDOPV with good ambient stability and large charge-transfer integrals for electrons, leading to a high electron mobility of up to 12.6 cm2 V−1 s−1 in air. As a service to our authors and readers, this journal provides supporting information supplied by the authors. Such materials are peer reviewed and may be re-organized for online delivery, but are not copy-edited or typeset. Technical support issues arising from supporting information (other than missing files) should be addressed to the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.
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Research context

OpenAlex topics: Organic and Molecular Conductors Research · Porphyrin and Phthalocyanine Chemistry · Molecular Junctions and Nanostructures

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Beijing National Laboratory for Molecular Sciences (BNLMS) Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education Center of Soft Matter Science and Engineering College of Chemistry and Molecular Engineering Peking University Beijing 100871 China

Key Laboratory of Organic Solids, Institute of Chemistry Chinese Academy of Sciences Beijing 100190 China

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